Synthesis of New Iminium Derivatives of Sulphonio-сloso-Decaborate Anion (Bu4N)[2-B10H9SC(NH2)R] (R = –CH3, –CH2CH3, –CH(CH3)2, –Ph, –PhCH3)
- Authors: Golubev A.V.1, Kubasov A.S.1, Lukoshkova A.A.1, Sarkisov N.A.1,2, Novikov I.V.1,2, Starodubets P.A.1,3, Bykov A.Y.1, Zhdanov A.P.1, Zhizhin K.Y.1, Kuznetsov N.T.1
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Affiliations:
- Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences
- MIREA—Russian Technological University
- Mendeleev University of Chemical Technology of Russia
- Issue: Vol 68, No 12 (2023)
- Pages: 1731-1739
- Section: КООРДИНАЦИОННЫЕ СОЕДИНЕНИЯ
- URL: https://journals.rcsi.science/0044-457X/article/view/231662
- DOI: https://doi.org/10.31857/S0044457X23601487
- EDN: https://elibrary.ru/XEXONU
- ID: 231662
Cite item
Abstract
New iminium derivatives of the sulfonio-closo-decaborate anion have been obtained in the form of tetrabutylammonium salts (Bu4N)[2-B10H9SC(NH2)R] (R = –CH3, –CH2CH3, –CH(CH3)2, –Ph, –PhCH3), in which the iminium group acts as a protective group and allows further modification of the boron cluster anion without acting the sulfonium group. The compounds have been studied by elemental analysis, IR and 11B, 1H, 13C NMR spectroscopies. The structure of compounds (Bu4N)[2-B10H9SC(NH2)CH3] and (Bu4N)[2-B10H9SC(NH2)Ph] has been confirmed by X-ray diffraction analysis. The yield of final compounds is >80%.
About the authors
A. V. Golubev
Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences
Email: golalekseival@mail.ru
119991, Moscow, Russia
A. S. Kubasov
Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences
Email: golalekseival@mail.ru
119991, Moscow, Russia
A. A. Lukoshkova
Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences
Email: golalekseival@mail.ru
119991, Moscow, Russia
N. A. Sarkisov
Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences; MIREA—Russian Technological University
Email: golalekseival@mail.ru
119991, Moscow, Russia; 119571, Moscow, Russia
I. V. Novikov
Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences; MIREA—Russian Technological University
Email: golalekseival@mail.ru
119991, Moscow, Russia; 119571, Moscow, Russia
P. A. Starodubets
Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences; Mendeleev University of Chemical Technology of Russia
Email: golalekseival@mail.ru
119991, Moscow, Russia; 125047, Moscow, Russia
A. Yu. Bykov
Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences
Email: golalekseival@mail.ru
119991, Moscow, Russia
A. P. Zhdanov
Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences
Email: golalekseival@mail.ru
119991, Moscow, Russia
K. Yu. Zhizhin
Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences
Email: golalekseival@mail.ru
119991, Moscow, Russia
N. T. Kuznetsov
Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences
Author for correspondence.
Email: golalekseival@mail.ru
119991, Moscow, Russia
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