Chemical Deposition of CdxPb1 – xS/CdyS Thin-Film Composite Structures
- Authors: Selyanina A.D.1, Maskaeva L.N.1,2, Voronin V.I.3, Anokhina I.A.4, Markov V.F.1,2
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Affiliations:
- Ural Federal University Named after First President of Russia B.N. Yeltsin
- Ural Institute of State Fire Service, the EMERCOM of Russia
- Mikheev Institute of Metal Physics, Ural Branch, Russian Academy of Sciences
- Institute of High-Temperature Electrochemistry, Ural Branch, Russian Academy of Sciences
- Issue: Vol 68, No 1 (2023)
- Pages: 26-33
- Section: СИНТЕЗ И СВОЙСТВА НЕОРГАНИЧЕСКИХ СОЕДИНЕНИЙ
- URL: https://journals.rcsi.science/0044-457X/article/view/136304
- DOI: https://doi.org/10.31857/S0044457X22601213
- EDN: https://elibrary.ru/GVQAAE
- ID: 136304
Cite item
Abstract
Thin films of CdxPb1 – xS (0 ≤ x ≤ 0.094) substitutional solid solutions of cubic structure B1 (space group Fm
) were prepared by chemical deposition and characterized by X-ray diffraction, scanning electron microscopy, EDX elemental analysis, and Raman spectroscopy. Once the cadmium sulfate concentration in the batch reached some critical value (0.1 mol/L), the films formed involved two autonomous phases: CdxPb1 – xS substitutional solid solutions and hexagonal cadmium sulfide CdyS of structure В4 (space group P63mc). The method and its parameters as proposed are efficient for manufacturing heterostructures in the CdS–PbS system in one-pot deposition.
About the authors
A. D. Selyanina
Ural Federal University Named after First President of Russia B.N. Yeltsin
Email: n-kutyavina@mail.ru
620002, Yekaterinburg, Russia
L. N. Maskaeva
Ural Federal University Named after First President of Russia B.N. Yeltsin; Ural Institute of State Fire Service, the EMERCOM of Russia
Email: n-kutyavina@mail.ru
620002, Yekaterinburg, Russia; 620062, Yekaterinburg, Russia
V. I. Voronin
Mikheev Institute of Metal Physics, Ural Branch, Russian Academy of Sciences
Email: n-kutyavina@mail.ru
620108, Yekaterinburg, Russia
I. A. Anokhina
Institute of High-Temperature Electrochemistry, Ural Branch, Russian Academy of Sciences
Email: n-kutyavina@mail.ru
620137, Yekaterinburg, Russia
V. F. Markov
Ural Federal University Named after First President of Russia B.N. Yeltsin; Ural Institute of State Fire Service, the EMERCOM of Russia
Author for correspondence.
Email: n-kutyavina@mail.ru
620002, Yekaterinburg, Russia; 620062, Yekaterinburg, Russia
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