Phase Equilibria Involving Solid Solutions in the Li–Eu–O System

G. A. Buzanov; Бузанов Г. А.; G. D. Nipan; Нипан Г. Д.

doi:10.31857/S0044457X23601566

Phase Equilibria Involving Solid Solutions in the Li–Eu–O System

Authors: Buzanov G.A.¹, Nipan G.D.¹
Affiliations:
1. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences
Issue: Vol 68, No 12 (2023)
Pages: 1816-1823
Section: ФИЗИКО-ХИМИЧЕСКИЙ АНАЛИЗ НЕОРГАНИЧЕСКИХ СИСТЕМ
URL: https://journals.rcsi.science/0044-457X/article/view/231682
DOI: https://doi.org/10.31857/S0044457X23601566
EDN: https://elibrary.ru/ZOBPGM
ID: 231682

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Abstract

Phase equilibria involving solid solutions in the Li–Eu–O system in an oxidizing, inert, and reducing atmospheres during annealing mixtures of various precursors subjected to preliminary mechanochemical activation at temperatures of 400–1100°C and partial pressures
~ 21 and 0.01 kPa and
~ 5 kPa have been studied by X-ray powder diffraction and thermogravimetry. The solubility of lithium in EuO has been first estimated, which is no less than 50–60%. For Eu2O3 and
, it is 30% of the total amount of cations. Along with LiEuO2, the formation of crystalline mixed-valent (EuII + EuIII) phases LiEu3O4 and Li2Eu5O8 has been confirmed. The thermal behavior of solid solutions Eu1 – xLixO1 – δ based on europium monoxide and Li1 + yEu3O4 – γ in air has been studied. The concentration phase diagram of the Li–Eu–O system has been constructed.

Keywords

phase diagrams, europium monoxide, multicomponent systems, spintronics, lithium hydride, solid-phase synthesis

About the authors

G. A. Buzanov

Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences

Email: gbuzanov@yandex.ru
119991, Moscow, Russia

G. D. Nipan

Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences

Author for correspondence.
Email: gbuzanov@yandex.ru
119991, Moscow, Russia

References

Matthias B.T., Bozorth R.M., Van Vleck J.H. // Phys. Rev. Lett. 1961. V. 7. № 5. P. 160. https://doi.org/10.1103/PhysRevLett.7.160
Schmehl A., Vaithyanathan V., Herrnberger A. et al. // Nature Mater. 2007. V. 6 P. 882. https://doi.org/10.1038/nmat2012
Steeneken P.G., Tjeng L.H., Elfimov I. et al. // Phys. Rev. Lett. 2002. V. 88. P. 047201. https://doi.org/10.1103/PhysRevLett.88.047201
Hasegawa Y. // Chem. Lett. 2013. V. 42. № 1. P. 2. https://doi.org/10.1246/cl.2013.2
Lettieri J., Vaithyanathan V., Eah S.K. et al. // Appl. Phys. Lett. 2003. V. 83. P. 975. https://doi.org/10.1063/1.1593832
Borukhovich A.S. // Mod. Electron. Mater. 2020. V. 6. № 3. P. 113. https://doi.org/10.3897/j.moem.6.3.54583
Borukhovich A.S., Troshin A.V. Europium Monoxide Semiconductor and Ferromagnet for Spintronics. Springer Series in Materials Science. Springer, 2018. V. 265. 189 p. https://doi.org/10.1007/978-3-319-76741-3
Королева Л.И. Магнитные полупроводники. М.: Физический факультет МГУ, 2003. 312 с.
Бамбуров В.Г., Борухович А.С., Самохвалов А.А. Введение в физико-химию ферромагнитных полупроводников. М.: Металлургия, 1988. 206 с.
Parfenov O.E., Averyanov D.V., Tokmachev A.M. et al. // J. Condens. Matter Phys. 2016. V. 28. № 22. P. 226001. https://doi.org/10.1088/0953-8984/28/22/226001
Kats V.N., Nefedov S.G., Shelukhin L.A. et al. // Appl. Mater. Today. 2020. V. 19. P. 100640. https://doi.org/10.1016/j.apmt.2020.100640
Kabanov V., Korenyuk S., Fedorenko Y. // Thin Solid Films. 2001. V. 400. № 1–2. P. 116. https://doi.org/10.1016/s0040-6090(01)01469-9
Hashimoto Y., Wakeshima M., Matsuhira K. et al. // Chem. Mater. 2002. V. 14. № 8. P. 3245. https://doi.org/10.1021/cm010728u
Waintal A., Gondrand M. // Mater. Res. Bull. 1967. V. 2. № 9. P. 889. https://doi.org/10.1016/0025-5408(67)90099-2
Julien C.M., Mauger A., Zaghib K., Groult H. // Inorganics. 2014. V. 2. № 1. P. 132. https://doi.org/10.3390/inorganics2010132
Cantwell J.R., Roof I.P., Smith M.D. et al. // Solid State Sci. 2011. V. 13. № 5. P. 1006. https://doi.org/10.1016/j.solidstatesciences.2011.02.001
Bärnighausen H. // Z. Anorg. Allg. Chem. 1970. V. 374. № 2. P. 201. https://doi.org/10.1002/zaac.19703740209
Bärnighausen H. // Z. Anorg. Allg. Chem. 1967. V. 349. № 5–6. P. 280 https://doi.org/10.1002/zaac.19673490508
Nyokong T., Greedan J.E. // Inorg. Chem. 1982. V. 21. № 1. P. 398. https://doi.org/10.1021/ic00131a071
Buzanov G.A., Nipan G.D., Zhizhin K.Yu., Kuznetsov N.T. // Russ. J. Inorg. Chem. 2017. V. 62. № 5. P. 551. https://doi.org/10.1134/s0036023617050059
Nipan G.D., Buzanov G.A., Zhizhin K.Y., Kuznetsov N.T. // Russ. J. Inorg. Chem. 2016. V. 61. № 14. P. 1689. https://doi.org/10.1134/s0036023616140035
Buzanov G.A., Nipan G.D., Zhizhin K.Y., Kuznetsov N.T. // Dokl. Chem. 2015. V. 465. V. 1. P. 268. https://doi.org/10.1134/s0012500815110063
Buzanov G.A., Nipan G.D. // Russ. J. Inorg. Chem. 2022. V. 67. P. 1035. https://doi.org/10.1134/S0036023622070051
Chang K., Hallstedt B. // CALPHAD. 2011. V. 35. P. 160. https://doi.org/10.1016/j.calphad.2011.02.003
Massalski T.B. Binary Alloy Phase Diagrams – 2nd edition. ASM International, Materials Park, Ohio, USA. 1990. 3589 p.
Казенас Е.К., Цветков Ю.В. Испарение оксидов. М.: Наука, 1997. 542 с.
Sun Y., Qiao Z. // High Temp. Mater. Process. 1999. V. 3. № 1. P. 125. https://doi.org/10.1615/HighTempMatProc.v3.i1.110
Rudolph D., Enseling D., Jüstel T., Schleid T. // Z. Anorg. Allg. Chem. 2017. V. 643. № 21. P. 1525. https://doi.org/10.1002/zaac.201700224
Nakajima H., Nohira T., Ito Y. // Electrochem. Solid-State Lett. 2004. V. 7. № 5. P. E27. https://doi.org/10.1149/1.1664052