Effect of Fluorine on Thermoluminescence in LiMgPO4

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Abstract

Fluorine-doped lithium magnesium phosphate has been studied for the first time. It has been shown that fluorine significantly enhances the intensity of thermally stimulated luminescence. To find the preferred positions of fluorine and structural distortions caused by aliovalent substitution, ab initio calculations have been performed, which demonstrate that fluorine is not included into the (PO4)3– anion; rather, it promotes the formation of clusters simultaneously containing lithium and fluorine ions.

About the authors

M. O. Kalinkin

Institute of Solid State Chemistry, Ural Branch, Russian Academy of Sciences

Email: kalinkin@ihim.uran.ru
620990, Yekaterinburg, Russia

D. A. Akulov

Institute of Solid State Chemistry, Ural Branch, Russian Academy of Sciences

Email: kalinkin@ihim.uran.ru
620990, Yekaterinburg, Russia

O. I. Gyrdasova

Institute of Solid State Chemistry, Ural Branch, Russian Academy of Sciences

Email: kalinkin@ihim.uran.ru
620990, Yekaterinburg, Russia

R. M. Abashev

Institute of Solid State Chemistry, Ural Branch, Russian Academy of Sciences; Ural Federal University named after the first President of Russia B.N. Yeltsin

Email: kalinkin@ihim.uran.ru
620990, Yekaterinburg, Russia; 620002, Yekaterinburg, Russia

A. I. Surdo

Institute of Solid State Chemistry, Ural Branch, Russian Academy of Sciences

Email: kalinkin@ihim.uran.ru
620990, Yekaterinburg, Russia

N. I. Medvedeva

Institute of Solid State Chemistry, Ural Branch, Russian Academy of Sciences

Email: kalinkin@ihim.uran.ru
620990, Yekaterinburg, Russia

D. G. Kellerman

Institute of Solid State Chemistry, Ural Branch, Russian Academy of Sciences

Author for correspondence.
Email: kalinkin@ihim.uran.ru
620990, Yekaterinburg, Russia

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Copyright (c) 2023 М.О. Калинкин, Д.А. Акулов, О.И. Гырдасова, Р.М. Абашев, А.И. Сюрдо, Н.И. Медведева, Д.Г. Келлерман

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