Synthesis, Structure, and Thermal Properties of Scandium(III) and Iron(III) Complexes with 3-Methyl-2,4-Pentanedione as Precursors for Chemical Gas-Phase Processes

A. M. Makarenko; Макаренко А. М.; N. V. Kuratieva; Куратьева Н. В.; D. P. Pishchur; Пищур Д. П.; K. V. Zherikova; Жерикова К. В.

doi:10.31857/S0044457X22601444

Synthesis, Structure, and Thermal Properties of Scandium(III) and Iron(III) Complexes with 3-Methyl-2,4-Pentanedione as Precursors for Chemical Gas-Phase Processes

Authors: Makarenko A.M.¹, Kuratieva N.V.¹, Pishchur D.P.¹, Zherikova K.V.¹
Affiliations:
1. Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences
Issue: Vol 68, No 2 (2023)
Pages: 221-228
Section: ФИЗИКО-ХИМИЧЕСКИЙ АНАЛИЗ НЕОРГАНИЧЕСКИХ СИСТЕМ
URL: https://journals.rcsi.science/0044-457X/article/view/136458
DOI: https://doi.org/10.31857/S0044457X22601444
EDN: https://elibrary.ru/LPGSNT
ID: 136458

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Abstract
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Abstract

Complexes Sc(Meacac)3 and Fe(Meacac)3 (Meacac is 3-methyl-2,4-pentanedionate anion) have been synthesized, and their crystal structures have been first determined by X-ray diffraction. The volatility and thermal stability of the obtained compounds have been studied. The temperature, enthalpy, and entropy of melting of the complexes have been determined by differential scanning calorimetry. The flow method has been used to obtain the temperature dependence of the saturated vapor pressure of Sc(Meacac)3 in the range 414–472 K, from which the thermodynamic characteristics of the sublimation process have been calculated at an average temperature (
= 132.8 ± 1.8 kJ/mol,
= 226.1 ± 4.6 J/(K mol)) and at 298.15 K (
= 143.9 ± 2.6 kJ/mol,
= 256.5 ± 6.4 J/(K mol)). The compounds studied can be used as precursors in chemical vapor deposition, and the set of obtained thermodynamic data can be used to select the optimal deposition conditions.

Keywords

β-diketonate, X-ray diffraction, saturated vapor pressure, enthalpy and entropy of sublimation and melting

References

Игуменов И.К., Чуманенко Ю.В., Земсков С.В. Проблемы химии и применения β-дикетонатов металлов / Под ред. Спицына В.И. М.: Наука, 1982. С. 100.
Громилов С.А. Байдина И.А. // Журн. структур. химии. 2004. Т. 45. № 6. С. 1076.
Moshier R.W., Sievers R.E. Gas Chromotography of Metal Chelates: International series of monographs in analytical chemistry. Pergamon Press: Oxford, 1967.
Жаркова Г.И., Стабников П.А., Сысоев С.А. и др. // Журн. структур. химии. 2005. Т. 46. № 2. С. 328.
Варнек В.А., Игуменов И.К., Стабников П.А. и др. // Журн. структур. химии. 2001. Т. 42. № 5. С. 1024.
Igumenov I.K., Basova T.V., Belosludov V.R. Application of Thermodynamics to Biological and Materials Science / Ed. Tadashi M. London: InTech, 2011. P. 521.
Stabnikov P.A., Alferova N.I., Korolkov I.V. et al. // J. Struct. Chem. 2020. V. 61. № 10. P. 1615. https://doi.org/10.1134/S0022476620100145
Robertson I., Truter M.R. // Inorg. Phys. Theor. 1967. P. 309.
Шапкин Н.П., Алехина О.Г., Реутов В.А. и др. // Журн. общ. химии. 1992. Т. 62. № 3. С. 505.
Abrahams B.F., Hoskins B.F., McFadyen D.W. et al. // Acta Crystallogr., Sect. C: Cryst. Struct. Commun. 1998. V. 54. № 12. P. 1807. https://doi.org/10.1107/S0108270198008592
Döhring A., Goddard R., Jolly P.W. et al. // Inorg. Chem. 1997. V. 36. № 2. P. 177. https://doi.org/10.1021/ic960441c
Berg M.A.G., Ritchie M.K., Merola J.S. // Polyhedron. 2012. V. 38. № 1. P. 126. https://doi.org/10.1016/j.poly.2012.02.024
Ribeiro da Silva M.A.V., Ferrao M.L.C.C.H., Silva R.M.G.E. da // J. Chem. Thermodyn. 1992. V. 24. P. 1293.
Zherikova K.V., Zelenina L.N., Chusova T.P. et al. // Phys. Procedia. 2013. V. 46. P. 200. https://doi.org/10.1016/j.phpro.2013.07.068
Zelenina L.N., Zherikova K.V., Chusova T.P. et al. // Thermochim. Acta. 2020. V. 689. P. 178639. https://doi.org/10.1016/j.tca.2020.178639
Zherikova K.V., Verevkin S.P. // RSC Adv. 2020. V. 10. № 63. P. 38158. https://doi.org/10.1039/d0ra06880b
Kong P., Pu Y., Ma P. et al. // Thin Solid Films. 2020. V. 714. P. 1. https://doi.org/10.1016/j.tsf.2020.138357
De Rouffignac P., Yousef A.P., Kim K.H. et al. // Electrochem. Solid-State Lett. 2006. V. 9. № 6. P. 45. https://doi.org/10.1149/1.2191131
Smirnova T.P., Yakovkina L.V., Borisov V.O. et al. // J. Struct. Chem. 2017. V. 58. № 8. P. 1573. https://doi.org/10.1134/S0022476617080145
Stognii A.I., Serokurova A.I., Smirnova M.N. et al. // Russ. J. Inorg. Chem. 2021. V. 66. № 12. P. 1822. https://doi.org/10.1134/S0036023621120196
Bumagin N.A. // Russ. J. Gen. Chem. 2022. V. 92. № 5. P. 832. https://doi.org/10.1134/S1070363222050127
Bruker AXS Inc. (2004). APEX2 (Version 1.08), SAINT (Version 7.03), and SADABS (Version 2.11). Bruker Advanced X-ray Solutions, Madison, Wisconsin, USA.
Sheldrick G.M. // Acta Crystallogr. 2015. V. C71. P. 3.
Zherikova K.V., Makarenko A.M., Karakovskaya K.I. et al. // Russ. J. Gen. Chem. V. 91. № 10. P. 1990. https://doi.org/10.1134/S1070363221100108
Anderson T.J., Neuman M.A., Melson G.A. // Inorg. Chem. 1973. V. 12. № 4. P. 927. https://doi.org/10.1021/ic50122a046
Diaz-Acosta I., Baker J., Cordes W. et al. // J. Phys. Chem. A. 2001. V. 105. № 1. P. 238. https://doi.org/10.1021/jp0028599
Beech G., Lintonbon R.M. // Thermochim. Acta. 1971. V. 3. P. 97.
Sabolović J., Mrak Ž., Koštrun S. et al. // Inorg. Chem. 2004. V. 43. № 26. P. 8479. https://doi.org/10.1021/ic048900u
Kulikov D., Verevkin S.P., Heintz A. // J. Chem. Eng. Data. 2001. V. 46. № 6. P. 1593. https://doi.org/10.1021/je010187p
Kulikov D., Verevkin S.P., Heintz A. // Fluid Phase Equilib. 2001. V. 192. № 1–2. P. 187. https://doi.org/10.1016/S0378-3812(01)00633-1
Zherikova K.V., Verevkin S.P. // Fluid Phase Equilib. 2018. V. 472. P. 196. https://doi.org/10.1016/j.fluid.2018.05.004
Verevkin S.P., Emel’yanenko V.N., Zherikova K.V. et al. // Chem. Phys. Lett. 2020. V. 739. P. 136911. https://doi.org/10.1016/j.cplett.2019.136911
Melia T.P., Merrifield R. // J. Inorg. Nucl. Chem. 1970. V. 32. P. 2573.
Verevkin S.P., Sazonova A.Y., Emel’yanenko V.N. et al. // J. Chem. Eng. Data. 2015. V. 60. P. 89. https://doi.org/doi.org/10.1021/je500784s