Synthesis, Structure, and Thermal Properties of Scandium(III) and Iron(III) Complexes with 3-Methyl-2,4-Pentanedione as Precursors for Chemical Gas-Phase Processes
- Авторлар: Makarenko A.1, Kuratieva N.1, Pishchur D.1, Zherikova K.1
-
Мекемелер:
- Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences
- Шығарылым: Том 68, № 2 (2023)
- Беттер: 221-228
- Бөлім: ФИЗИКО-ХИМИЧЕСКИЙ АНАЛИЗ НЕОРГАНИЧЕСКИХ СИСТЕМ
- URL: https://journals.rcsi.science/0044-457X/article/view/136458
- DOI: https://doi.org/10.31857/S0044457X22601444
- EDN: https://elibrary.ru/LPGSNT
- ID: 136458
Дәйексөз келтіру
Аннотация
Complexes Sc(Meacac)3 and Fe(Meacac)3 (Meacac is 3-methyl-2,4-pentanedionate anion) have been synthesized, and their crystal structures have been first determined by X-ray diffraction. The volatility and thermal stability of the obtained compounds have been studied. The temperature, enthalpy, and entropy of melting of the complexes have been determined by differential scanning calorimetry. The flow method has been used to obtain the temperature dependence of the saturated vapor pressure of Sc(Meacac)3 in the range 414–472 K, from which the thermodynamic characteristics of the sublimation process have been calculated at an average temperature (
= 132.8 ± 1.8 kJ/mol,
= 226.1 ± 4.6 J/(K mol)) and at 298.15 K (
= 143.9 ± 2.6 kJ/mol,
= 256.5 ± 6.4 J/(K mol)). The compounds studied can be used as precursors in chemical vapor deposition, and the set of obtained thermodynamic data can be used to select the optimal deposition conditions.
Авторлар туралы
A. Makarenko
Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences
Email: ksenia@niic.nsc.ru
630090, Novosibirsk, Russia
N. Kuratieva
Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences
Email: ksenia@niic.nsc.ru
630090, Novosibirsk, Russia
D. Pishchur
Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences
Email: ksenia@niic.nsc.ru
630090, Novosibirsk, Russia
K. Zherikova
Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences
Хат алмасуға жауапты Автор.
Email: ksenia@niic.nsc.ru
630090, Novosibirsk, Russia
Әдебиет тізімі
- Игуменов И.К., Чуманенко Ю.В., Земсков С.В. Проблемы химии и применения β-дикетонатов металлов / Под ред. Спицына В.И. М.: Наука, 1982. С. 100.
- Громилов С.А. Байдина И.А. // Журн. структур. химии. 2004. Т. 45. № 6. С. 1076.
- Moshier R.W., Sievers R.E. Gas Chromotography of Metal Chelates: International series of monographs in analytical chemistry. Pergamon Press: Oxford, 1967.
- Жаркова Г.И., Стабников П.А., Сысоев С.А. и др. // Журн. структур. химии. 2005. Т. 46. № 2. С. 328.
- Варнек В.А., Игуменов И.К., Стабников П.А. и др. // Журн. структур. химии. 2001. Т. 42. № 5. С. 1024.
- Igumenov I.K., Basova T.V., Belosludov V.R. Application of Thermodynamics to Biological and Materials Science / Ed. Tadashi M. London: InTech, 2011. P. 521.
- Stabnikov P.A., Alferova N.I., Korolkov I.V. et al. // J. Struct. Chem. 2020. V. 61. № 10. P. 1615. https://doi.org/10.1134/S0022476620100145
- Robertson I., Truter M.R. // Inorg. Phys. Theor. 1967. P. 309.
- Шапкин Н.П., Алехина О.Г., Реутов В.А. и др. // Журн. общ. химии. 1992. Т. 62. № 3. С. 505.
- Abrahams B.F., Hoskins B.F., McFadyen D.W. et al. // Acta Crystallogr., Sect. C: Cryst. Struct. Commun. 1998. V. 54. № 12. P. 1807. https://doi.org/10.1107/S0108270198008592
- Döhring A., Goddard R., Jolly P.W. et al. // Inorg. Chem. 1997. V. 36. № 2. P. 177. https://doi.org/10.1021/ic960441c
- Berg M.A.G., Ritchie M.K., Merola J.S. // Polyhedron. 2012. V. 38. № 1. P. 126. https://doi.org/10.1016/j.poly.2012.02.024
- Ribeiro da Silva M.A.V., Ferrao M.L.C.C.H., Silva R.M.G.E. da // J. Chem. Thermodyn. 1992. V. 24. P. 1293.
- Zherikova K.V., Zelenina L.N., Chusova T.P. et al. // Phys. Procedia. 2013. V. 46. P. 200. https://doi.org/10.1016/j.phpro.2013.07.068
- Zelenina L.N., Zherikova K.V., Chusova T.P. et al. // Thermochim. Acta. 2020. V. 689. P. 178639. https://doi.org/10.1016/j.tca.2020.178639
- Zherikova K.V., Verevkin S.P. // RSC Adv. 2020. V. 10. № 63. P. 38158. https://doi.org/10.1039/d0ra06880b
- Kong P., Pu Y., Ma P. et al. // Thin Solid Films. 2020. V. 714. P. 1. https://doi.org/10.1016/j.tsf.2020.138357
- De Rouffignac P., Yousef A.P., Kim K.H. et al. // Electrochem. Solid-State Lett. 2006. V. 9. № 6. P. 45. https://doi.org/10.1149/1.2191131
- Smirnova T.P., Yakovkina L.V., Borisov V.O. et al. // J. Struct. Chem. 2017. V. 58. № 8. P. 1573. https://doi.org/10.1134/S0022476617080145
- Stognii A.I., Serokurova A.I., Smirnova M.N. et al. // Russ. J. Inorg. Chem. 2021. V. 66. № 12. P. 1822. https://doi.org/10.1134/S0036023621120196
- Bumagin N.A. // Russ. J. Gen. Chem. 2022. V. 92. № 5. P. 832. https://doi.org/10.1134/S1070363222050127
- Bruker AXS Inc. (2004). APEX2 (Version 1.08), SAINT (Version 7.03), and SADABS (Version 2.11). Bruker Advanced X-ray Solutions, Madison, Wisconsin, USA.
- Sheldrick G.M. // Acta Crystallogr. 2015. V. C71. P. 3.
- Zherikova K.V., Makarenko A.M., Karakovskaya K.I. et al. // Russ. J. Gen. Chem. V. 91. № 10. P. 1990. https://doi.org/10.1134/S1070363221100108
- Anderson T.J., Neuman M.A., Melson G.A. // Inorg. Chem. 1973. V. 12. № 4. P. 927. https://doi.org/10.1021/ic50122a046
- Diaz-Acosta I., Baker J., Cordes W. et al. // J. Phys. Chem. A. 2001. V. 105. № 1. P. 238. https://doi.org/10.1021/jp0028599
- Beech G., Lintonbon R.M. // Thermochim. Acta. 1971. V. 3. P. 97.
- Sabolović J., Mrak Ž., Koštrun S. et al. // Inorg. Chem. 2004. V. 43. № 26. P. 8479. https://doi.org/10.1021/ic048900u
- Kulikov D., Verevkin S.P., Heintz A. // J. Chem. Eng. Data. 2001. V. 46. № 6. P. 1593. https://doi.org/10.1021/je010187p
- Kulikov D., Verevkin S.P., Heintz A. // Fluid Phase Equilib. 2001. V. 192. № 1–2. P. 187. https://doi.org/10.1016/S0378-3812(01)00633-1
- Zherikova K.V., Verevkin S.P. // Fluid Phase Equilib. 2018. V. 472. P. 196. https://doi.org/10.1016/j.fluid.2018.05.004
- Verevkin S.P., Emel’yanenko V.N., Zherikova K.V. et al. // Chem. Phys. Lett. 2020. V. 739. P. 136911. https://doi.org/10.1016/j.cplett.2019.136911
- Melia T.P., Merrifield R. // J. Inorg. Nucl. Chem. 1970. V. 32. P. 2573.
- Verevkin S.P., Sazonova A.Y., Emel’yanenko V.N. et al. // J. Chem. Eng. Data. 2015. V. 60. P. 89. https://doi.org/doi.org/10.1021/je500784s
Қосымша файлдар
![](/img/style/loading.gif)