Thermal Stability of Nanocrystalline Zinc Sulfide ZnS

S. I. Sadovnikov; Садовников С. И.; S. V. Sergeeva; Сергеева С. В.

doi:10.31857/S0044457X22601936

Thermal Stability of Nanocrystalline Zinc Sulfide ZnS

Authors: Sadovnikov S.I.¹, Sergeeva S.V.²
Affiliations:
1. Institute of Solid-State Chemistry, Ural Branch, Russian Academy of Sciences
2. Institute of Metallurgy, Ural Branch, Russian Academy of Sciences
Issue: Vol 68, No 4 (2023)
Pages: 444-451
Section: СИНТЕЗ И СВОЙСТВА НЕОРГАНИЧЕСКИХ СОЕДИНЕНИЙ
URL: https://journals.rcsi.science/0044-457X/article/view/136317
DOI: https://doi.org/10.31857/S0044457X22601936
EDN: https://elibrary.ru/FMNDHO
ID: 136317

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Abstract
About the authors
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Abstract

Nanocrystalline zinc sulfide (ZnS) powders are prepared via hydrothermal deposition from aqueous solutions of zinc nitrate and sodium sulfide in the presence of sodium citrate or Trilon B. The average particle sizes of the product ZnS nanopowders ranging from 2 to 9 nm are tuned via varying the batch concentrations of the reagents. Air-annealing of as-prepared ZnS nanopowders at temperatures of 280 to 530°C oxidizes cubic zinc sulfide to hexagonal zinc oxide. The oxidation of the finest-grained zinc sulfide nanopowders having a particle size of 2 nm starts at 280–330°C, while the coarsest-grained nanopowder having a particle size of 9 nm starts to oxidize at 530°C. In the coarsest-grained ZnS powder, the particle size increases as little as from 9 to 12 nm when temperature rises to 530°C, while the finest-grained nanopowders have their particle sizes increase from 2 to 9 nm in response to the same rise in temperature.

Keywords

chemical deposition, phase and size stability, zinc oxide

About the authors

S. I. Sadovnikov

Institute of Solid-State Chemistry, Ural Branch, Russian Academy of Sciences

Email: sadovnikov@ihim.uran.ru
620990, Yekaterinburg, Russia

S. V. Sergeeva

Institute of Metallurgy, Ural Branch, Russian Academy of Sciences

Author for correspondence.
Email: sadovnikov@ihim.uran.ru
620016, Yekaterinburg, Russia

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