New Solvate Polymorphs of Lanthanide Trisacetylacetonates: Crystal Structures of [Ln(acac) 3 (H 2 O) 2 ] · Solv (Ln = Eu, Dy; Solv = Thf, H 2 O + EtOH, MeOH)

A. B. Ilyukhin; A. V. Gavrikov; Zh. V. Dobrokhotova; V. M. Novotortsev

doi:10.1134/S003602361809005X

New Solvate Polymorphs of Lanthanide Trisacetylacetonates: Crystal Structures of [Ln(acac)₃(H₂O)₂] · Solv (Ln = Eu, Dy; Solv = Thf, H₂O + EtOH, MeOH)

作者: Ilyukhin A.B.¹, Gavrikov A.V.¹, Dobrokhotova Z.V.¹, Novotortsev V.M.¹
隶属关系:
1. Kurnakov Institute of General and Inorganic Chemistry
期: 卷 63, 编号 9 (2018)
页面: 1186-1191
栏目: Coordination Compounds
URL: https://journals.rcsi.science/0036-0236/article/view/168976
DOI: https://doi.org/10.1134/S003602361809005X
ID: 168976

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Solvate polymorphs of [Dy(acac)₃(H₂O)₂] · Thf, [Ln(acac)₃(H₂O)₂] · H₂O · EtOH (Ln = Eu, Dy) and [Dy(acac)₃(H₂O)₂] · 1.5MeOH, which belongs to a new structural type, are isolated as single crystals. The structures of the prepared compounds are determined by X-ray crystallography, and the effect of solvate molecules on their crystal structures is discussed.