Email this article New Solvate Polymorphs of Lanthanide Trisacetylacetonates: Crystal Structures of [Ln(acac)3(H2O)2] · Solv (Ln = Eu, Dy; Solv = Thf, H2O + EtOH, MeOH)
- Authors: Ilyukhin A.B.1, Gavrikov A.V.1, Dobrokhotova Z.V.1, Novotortsev V.M.1
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Affiliations:
- Kurnakov Institute of General and Inorganic Chemistry
- Issue: Vol 63, No 9 (2018)
- Pages: 1186-1191
- Section: Coordination Compounds
- URL: https://journals.rcsi.science/0036-0236/article/view/168976
- DOI: https://doi.org/10.1134/S003602361809005X
- ID: 168976
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Abstract
Solvate polymorphs of [Dy(acac)3(H2O)2] · Thf, [Ln(acac)3(H2O)2] · H2O · EtOH (Ln = Eu, Dy) and [Dy(acac)3(H2O)2] · 1.5MeOH, which belongs to a new structural type, are isolated as single crystals. The structures of the prepared compounds are determined by X-ray crystallography, and the effect of solvate molecules on their crystal structures is discussed.
About the authors
A. B. Ilyukhin
Kurnakov Institute of General and Inorganic Chemistry
Author for correspondence.
Email: ilyukhin@gmail.com
Russian Federation, Moscow, 119991
A. V. Gavrikov
Kurnakov Institute of General and Inorganic Chemistry
Email: ilyukhin@gmail.com
Russian Federation, Moscow, 119991
Zh. V. Dobrokhotova
Kurnakov Institute of General and Inorganic Chemistry
Email: ilyukhin@gmail.com
Russian Federation, Moscow, 119991
V. M. Novotortsev
Kurnakov Institute of General and Inorganic Chemistry
Email: ilyukhin@gmail.com
Russian Federation, Moscow, 119991
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