New Solvate Polymorphs of Lanthanide Trisacetylacetonates: Crystal Structures of [Ln(acac)3(H2O)2] · Solv (Ln = Eu, Dy; Solv = Thf, H2O + EtOH, MeOH)


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Resumo

Solvate polymorphs of [Dy(acac)3(H2O)2] · Thf, [Ln(acac)3(H2O)2] · H2O · EtOH (Ln = Eu, Dy) and [Dy(acac)3(H2O)2] · 1.5MeOH, which belongs to a new structural type, are isolated as single crystals. The structures of the prepared compounds are determined by X-ray crystallography, and the effect of solvate molecules on their crystal structures is discussed.

Sobre autores

A. Ilyukhin

Kurnakov Institute of General and Inorganic Chemistry

Autor responsável pela correspondência
Email: ilyukhin@gmail.com
Rússia, Moscow, 119991

A. Gavrikov

Kurnakov Institute of General and Inorganic Chemistry

Email: ilyukhin@gmail.com
Rússia, Moscow, 119991

Zh. Dobrokhotova

Kurnakov Institute of General and Inorganic Chemistry

Email: ilyukhin@gmail.com
Rússia, Moscow, 119991

V. Novotortsev

Kurnakov Institute of General and Inorganic Chemistry

Email: ilyukhin@gmail.com
Rússia, Moscow, 119991

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