Influence of Synthesis Conditions on the Performance of Palladium–Copper Ethanol-to-Butanol Conversion Catalysts
- Autores: Nikolaev S.1, Ezzhelenko D.1, Chistyakov A.2, Chistyakova P.2, Tsodikov M.2
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Afiliações:
- Department of Chemistry, Moscow State University
- Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences
- Edição: Volume 63, Nº 4 (2023)
- Páginas: 566-581
- Seção: Articles
- URL: https://journals.rcsi.science/0028-2421/article/view/249418
- DOI: https://doi.org/10.31857/S0028242123040111
- EDN: https://elibrary.ru/OMKRKY
- ID: 249418
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Resumo
The influence of the synthesis conditions on the performance of Pd–Cu ethanol-to-butanol conversion catalysts was studied. The optimum conditions for forming the most active system 0.2%Cu/0.3%Pd/Al2O3 are as follows: sample synthesis by Al2O3 impregnation from aqueous solutions of Pd and Cu nitrates; deposition of the metal precursors in succession; total content of Pd and Cu in the sample 0.5 wt %; Pd : Сu molar ratio 1 : 1; catalyst reduction temperature 200○С. As shown by TEM, XPS, TPD-NH3, TPR-H2, XRD, and N2 adsorption, the surface of the most active catalyst contains Pd0Cu0 particles with the mean size of 4 ± 2 nm. The bimetallic particles are an alloy with the fcc structure and Pd : Cu ratio of 40 : 60. At 275○C, the performance of 0.2%Cu/0.3%Pd/Al2O3 is 182 × 10–4 mol h–1 g–1. The value obtained is higher by several orders of magnitude than the performance of the reference catalysts M1/Al2O3 (M1 = Fe, Ni, Co) and by an order of magnitude than that of the reference catalysts M2/Al2O3 (M2 = Ru, Rh, Pt, Pd, Pt–Re, Ni–Mo).
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Sobre autores
S. Nikolaev
Department of Chemistry, Moscow State University
Email: serge2000@rambler.ru
119991, Moscow, Russia
D. Ezzhelenko
Department of Chemistry, Moscow State University
Email: petrochem@ips.ac.ru
119991, Moscow, Russia
A. Chistyakov
Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences
Email: petrochem@ips.ac.ru
119991, Moscow, Russia
P. Chistyakova
Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences
Email: petrochem@ips.ac.ru
119991, Moscow, Russia
M. Tsodikov
Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences
Autor responsável pela correspondência
Email: petrochem@ips.ac.ru
119991, Moscow, Russia
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