Dehydrogenation of Ethylbenzene to Styrene over Rhenium- and Tungsten-Containing Porous Ceramic Converters
- Authors: Fedotov A.S.1, Grachev D.Y.1, Bagdatov R.A.1, Tsodikov M.V.1, Uvarov V.I.2, Kapustin R.D.2, Pol' S.3, Dyumen'il' F.3
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Affiliations:
- Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences
- Merzhanov Institute of Structural Macrokinetics and Materials Science, Russian Academy of Sciences
- Universita. Lille, CNRS, Centrale Lille, Univ. Artois, UMR 8181 – UCCS – Unité de Catalyse et Chimie du Solide
- Issue: Vol 63, No 2 (2023)
- Pages: 250-261
- Section: Articles
- URL: https://journals.rcsi.science/0028-2421/article/view/141896
- DOI: https://doi.org/10.31857/S0028242123020090
- EDN: https://elibrary.ru/HKTGKM
- ID: 141896
Cite item
Abstract
A series of tubular porous ceramic converters modified with mono- and bimetallic catalytic systems based on rhenium and tungsten were prepared by a combination of self-propagating high-temperature synthesis and the sol–gel method. These converters were tested in dehydrogenation of ethylbenzene to styrene. Among the tested samples, a monometallic tungsten-containing converter exhibited the optimal properties as it achieved the highest target product production performance. Within the temperature range of 550–600°C, this converter provided a yield of styrene up to about 15 wt % and styrene productivity up to about 22 g h–1 dm–3, with the carbonization of the sample not exceeding 5 wt % over about 6 h of reaction.
About the authors
A. S. Fedotov
Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences
Email: alexey.fedotov@ips.ac.ru
119991, Moscow, Russia
D. Yu. Grachev
Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences
Email: petrochem@ips.ac.ru
119991, Moscow, Russia
R. A. Bagdatov
Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences
Email: petrochem@ips.ac.ru
119991, Moscow, Russia
M. V. Tsodikov
Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences
Email: petrochem@ips.ac.ru
119991, Moscow, Russia
V. I. Uvarov
Merzhanov Institute of Structural Macrokinetics and Materials Science, Russian Academy of Sciences
Email: petrochem@ips.ac.ru
142432, Chernogolovka, Russia
R. D. Kapustin
Merzhanov Institute of Structural Macrokinetics and Materials Science, Russian Academy of Sciences
Email: petrochem@ips.ac.ru
142432, Chernogolovka, Russia
S. Pol'
Universita. Lille, CNRS, Centrale Lille, Univ. Artois, UMR 8181 – UCCS – Unité de Catalyse et Chimie du Solide
Email: petrochem@ips.ac.ru
F-59000, Lille, France
F. Dyumen'il'
Universita. Lille, CNRS, Centrale Lille, Univ. Artois, UMR 8181 – UCCS – Unité de Catalyse et Chimie du Solide
Author for correspondence.
Email: petrochem@ips.ac.ru
F-59000, Lille, France
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