Dehydrogenation of Ethylbenzene to Styrene over Rhenium- and Tungsten-Containing Porous Ceramic Converters

Мұқаба

Дәйексөз келтіру

Толық мәтін

Ашық рұқсат Ашық рұқсат
Рұқсат жабық Рұқсат берілді
Рұқсат жабық Тек жазылушылар үшін

Аннотация

A series of tubular porous ceramic converters modified with mono- and bimetallic catalytic systems based on rhenium and tungsten were prepared by a combination of self-propagating high-temperature synthesis and the sol–gel method. These converters were tested in dehydrogenation of ethylbenzene to styrene. Among the tested samples, a monometallic tungsten-containing converter exhibited the optimal properties as it achieved the highest target product production performance. Within the temperature range of 550–600°C, this converter provided a yield of styrene up to about 15 wt % and styrene productivity up to about 22 g h–1 dm–3, with the carbonization of the sample not exceeding 5 wt % over about 6 h of reaction.

Авторлар туралы

A. Fedotov

Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences

Email: alexey.fedotov@ips.ac.ru
119991, Moscow, Russia

D. Grachev

Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences

Email: petrochem@ips.ac.ru
119991, Moscow, Russia

R. Bagdatov

Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences

Email: petrochem@ips.ac.ru
119991, Moscow, Russia

M. Tsodikov

Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences

Email: petrochem@ips.ac.ru
119991, Moscow, Russia

V. Uvarov

Merzhanov Institute of Structural Macrokinetics and Materials Science, Russian Academy of Sciences

Email: petrochem@ips.ac.ru
142432, Chernogolovka, Russia

R. Kapustin

Merzhanov Institute of Structural Macrokinetics and Materials Science, Russian Academy of Sciences

Email: petrochem@ips.ac.ru
142432, Chernogolovka, Russia

S. Pol'

Universita. Lille, CNRS, Centrale Lille, Univ. Artois, UMR 8181 – UCCS – Unité de Catalyse et Chimie du Solide

Email: petrochem@ips.ac.ru
F-59000, Lille, France

F. Dyumen'il'

Universita. Lille, CNRS, Centrale Lille, Univ. Artois, UMR 8181 – UCCS – Unité de Catalyse et Chimie du Solide

Хат алмасуға жауапты Автор.
Email: petrochem@ips.ac.ru
F-59000, Lille, France

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