Diversity of fundamental building blocks [M(IO3)6] in iodate families and new trigonal polymorph of Cs2HIn(IO3)6
- Autores: Reutova O.1, Belokoneva E.1, Volkov A.2, Dimitrova О.1
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Afiliações:
- Lomonosov Moscow State University
- Skolkovo Institute of Science and Technology
- Edição: Volume 69, Nº 4 (2024)
- Páginas: 597-611
- Seção: СТРУКТУРА НЕОРГАНИЧЕСКИХ СОЕДИНЕНИЙ
- URL: https://journals.rcsi.science/0023-4761/article/view/264363
- DOI: https://doi.org/10.31857/S0023476124040052
- EDN: https://elibrary.ru/XDNNAG
- ID: 264363
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Resumo
Crystals of new structural high-symmetry modification of Cs2HIn(IO3)6, which crystallyzes in sp. gr. R3 with parameters of unit cell a = 11.8999(4), c = 11.6513(5) Å were obtained in hydrothermal conditions. Crystal chemical comparison with triclinic modification the investigated earlier was carried out. Both structures are composed of isolated blocks [In(IO3)6]3–. The new modification belongs to the family of trigonal iodates isostructural to K2Ge(IO3)6 compound. Local symmetry of separated blocks [M(IO3)6] (M = Ge, Ti, Sn, Ga, In and other metals) are analyzed. Structural systematic of iodate families is suggested on the base of comparative crystal chemical analysis. The influence of cation composition and synthesis conditions on symmetry and topology of crystal structures as well as local symmetry of blocks on physical properties of compounds are discussed.
Sobre autores
O. Reutova
Lomonosov Moscow State University
Email: elbel@geol.msu.ru
Geological Faculty, Department of Crystallography and Crystal Chemistry
Rússia, MoscowE. Belokoneva
Lomonosov Moscow State University
Autor responsável pela correspondência
Email: elbel@geol.msu.ru
Geological Faculty, Department of Crystallography and Crystal Chemistry
Rússia, MoscowA. Volkov
Skolkovo Institute of Science and Technology
Email: elbel@geol.msu.ru
Rússia, Moscow
О. Dimitrova
Lomonosov Moscow State University
Email: elbel@geol.msu.ru
Geological Faculty, Department of Crystallography and Crystal Chemistry
Rússia, MoscowBibliografia
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