Diversity of fundamental building blocks [M(IO3)6] in iodate families and new trigonal polymorph of Cs2HIn(IO3)6

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Abstract

Crystals of new structural high-symmetry modification of Cs2HIn(IO3)6, which crystallyzes in sp. gr. R3 with parameters of unit cell a = 11.8999(4), c = 11.6513(5) Å were obtained in hydrothermal conditions. Crystal chemical comparison with triclinic modification the investigated earlier was carried out. Both structures are composed of isolated blocks [In(IO3)6]3–. The new modification belongs to the family of trigonal iodates isostructural to K2Ge(IO3)6 compound. Local symmetry of separated blocks [M(IO3)6] (M = Ge, Ti, Sn, Ga, In and other metals) are analyzed. Structural systematic of iodate families is suggested on the base of comparative crystal chemical analysis. The influence of cation composition and synthesis conditions on symmetry and topology of crystal structures as well as local symmetry of blocks on physical properties of compounds are discussed.

About the authors

O. V. Reutova

Lomonosov Moscow State University

Email: elbel@geol.msu.ru

Geological Faculty, Department of Crystallography and Crystal Chemistry

Russian Federation, Moscow

E. L. Belokoneva

Lomonosov Moscow State University

Author for correspondence.
Email: elbel@geol.msu.ru

Geological Faculty, Department of Crystallography and Crystal Chemistry

Russian Federation, Moscow

A. S. Volkov

Skolkovo Institute of Science and Technology

Email: elbel@geol.msu.ru
Russian Federation, Moscow

О. V. Dimitrova

Lomonosov Moscow State University

Email: elbel@geol.msu.ru

Geological Faculty, Department of Crystallography and Crystal Chemistry

Russian Federation, Moscow

References

  1. Sun C.-F., Yang B.-P., Mao J.-G. // Sci. China Chem. 2011. V. 54. P. 911. https://doi.org/10.1007/s11426-011-4289-8
  2. Hu C.-L., Mao J.-G. // Coord. Chem. Rev. 2015. V. 288. P. 1. https://doi.org/10.1016/j.ccr.2015.01.005
  3. Guo S.-P., Chi Y., Guo G.-C. // Coord. Chem. Rev. 2017. V. 335. P. 44. https://doi.org/10.1016/j.ccr.2016.12.013
  4. Mao F.-F., Hu C.-L., Chen J. et al. // Chem. Commun. 2019. V. 55. P. 6906. https://doi.org/10.1039/c9cc02774b
  5. Jia Y.-J., Chen Y.-G., Guo Y. et al. // Angew. Chem. Int. Ed. 2019. V. 58. № 48. P. 17194. https://doi.org/10.1002/ange.201908935
  6. Chen J., Hu C.-L., Mao F.-F. et al. // Chem. Sci. 2019. V. 10. P. 10870. https://doi.org/10.1039/c9sc04832d
  7. Reutova O., Belokoneva E., Volkov A. et al. // Symmetry. 2022. V. 14. P. 1699. https://doi.org/10.3390/sym14081699
  8. Wu C., Lin L., Jiang X.X. et al. // Chem. Mater. 2019. V. 31. № 24. P. 10100. https://doi.org/10.1021/acs.chemmater.9b03214
  9. Abudouwufu T., Zhang M., Cheng S.C. et al. // Eur. J. Inorg. Chem. 2019. V. 25. P. 1221. https://doi.org/10.1002/chem.201804995
  10. Luo M., Liang F., Hao X. et al. // Chem. Mater. 2020. V. 32. № 6. P. 2615. https://doi.org/10.1021/acs.chemmater.0c00196
  11. Fan H.X., Lin C.S., Chen K.C. et al. // Angew. Chem. 2020. V. 59. P. 5268. https://doi.org/10.1002/anie.201913287
  12. Chen J., Hu C.-L., Mao F.-F. et al. // Angew. Chem. Int. Ed. 2019. V. 58. P. 2098. https://doi.org/10.1002/anie.201813968
  13. Cao Z., Yue Y., Yao J. et al. // Inorg. Chem. 2011. V. 50. № 24. P. 12818. https://doi.org/10.1021/ic201991m
  14. Wu Q., Liu H., Jiang F. et al. // Chem. Mater. 2016. V. 28. P. 1413. https://doi.org/10.1021/acs.chemmater.5b04511
  15. Zhang M., Hu C., Abudouwufu T. et al. // Chem. Mater. 2018. V. 30. P. 1136. https://doi.org/10.1021/acs.chemmater.7b05252
  16. Mao F.-F., Hu C.-L., Chen J. et al. // Inorg. Chem. 2019. V. 58. P. 3982. https://doi.org/10.1021/acs.inorgchem.9b00075
  17. Chen J., Hu C.-L., Mao F.-F. et al. // Angew. Chem. Commun. 2019 V. 58. P. 11666. https://doi.org/10.1002/anie.201904383
  18. Xu Y., Zhou Y., Lin C. et al. // Cryst. Growth Des. 2021. V. 21. P. 7098. https://doi.org/10.1021/acs.cgd.1c00992
  19. De Boer J.L., van Bolhuis F., Olthof-Hazekamp R.V. // Acta Cryst. 1966. V. 21 (5). P. 841. https://doi.org/10.1107/s0365110x66004031
  20. Liminga R., Abrahams S.C., Bernstein J.L. // J. Chem. Phys. 1975. V. 62. P. 4388. https://doi.org/10.1063/1.430339
  21. Jansen M. // Solid State Chem. 1976. V. 17. P. 1.
  22. Liang J.K., Wang C.G. // Acta Chim. Sin. 1982. V. 40. P. 985.
  23. Schellhaas F., Hartl H.T., Frydrych R. // Acta Cryst. B. 1972. V. 28. № 9. P. 2834.
  24. Phanon D., Bentria B., Jeanneau E. et al. // Z. Krist. 2006. V. 221. P. 635.
  25. Phanon D., Mosset A., Gautier-Luneau I. // J. Mater. Chem. 2007. V. 17. № 11. P. 1123. https://doi.org/10.1039/B612677D
  26. Shehee T.C., Pehler S.F., Albrecht-Schmitt T.E. // J. Alloys Compd. 2005. V. 388. P. 225. https://doi.org/10.1016/j.jallcom.2004.07.037
  27. Chang H.-Y., Kim S.-H., Ok K.M., Halasyamani P.S. // J. Am. Chem. Soc. 2009. V. 131. № 19. P. 6865. https://doi.org/10.1021/ja9015099
  28. Sun C.-F., Hu C.-L., Kong F. et al. // Dalton Trans. 2010. V. 39. P. 1473. https://doi.org/10.1039/B917907K
  29. Kim Y.H., Tran T.T., Halasyamani P.S., Ok K.M. // Inorg. Chem. Front. 2015. V. 2. P. 361. https://doi.org/10.1039/C4QI00243A
  30. Yang B.P., Hu C.L., Xu X., Mao J.G. // Inorg. Chem. 2016. V. 55. № 5. P. 2481. https://doi.org/10.1021/acs.inorgchem.5b02859
  31. Liu H., Jiang X., Wang X. et al. // J. Mater. Chem. C. 2018. V. 6. P. 4698. https://doi.org/10.1039/c8tc00851e
  32. Liu K., Han J., Huang J. et al. // RSC Adv. 2021. V. 11. P. 10309. https://doi.org/10.1039/d0ra10726c
  33. Ok K.M., Halasyamani P.S. // Inorg. Chem. 2005. V. 44. P. 2263. https://doi.org/10.1021/ic048428c
  34. Belokoneva E.L., Karamysheva A.S., Dimitrova O.V., Volkov A.S. // Crystallography Reports. 2018. V. 63. P. 734. https://doi.org/10.1134/S1063774518050048
  35. Xiao L., You F., Gong P. et al. // Cryst. Eng. Commun. 2019. V. 21. P. 4981. https://doi.org/10.1039/c9ce00814d
  36. Liu X., Li G., Hu Y. et al. // Cryst. Growth Des. 2008. V. 8. № 7. P. 2453. https://doi.org/10.1021/cg800034z
  37. Mitoudi Vagourdi E., Zhang W., Denisova K. et al. // ACS Omega. 2020. V. 5. № 10. P. 5235. https://doi.org/10.1021/acsomega.9b04288
  38. Yang B.-P., Sun C.-F., Hu C.-L., Mao J.-G. // Dalton Trans. 2011. V. 40. № 5. P. 1055. https://doi.org/10.1039/c0dt01272f
  39. Реутова О.В., Белоконева Е.Л., Димитрова О.В., Волков А.С. // Кристаллография. 2020. T. 65. № 3. C. 441. https://doi.org/10.31857/S0023476120030273
  40. Park G., Byun H.R., Jang J.I., Ok K.M. // Chem. Mater. 2020. V. 32. P. 3621. https://doi.org/10.1021/acs.chemmater.0c01054
  41. Xu X., Hu C.-L., Yang B.-P., Mao J.-G. // CrystEngComm. 2013. V. 15. № 38. P. 7776. https://doi.org/10.1039/C3CE41185K
  42. Белоконева Е.Л., Карамышева А.С., Димитрова О.В., Волков А.С. // Кристаллография. 2018. Т. 63. № 1. С. 59. https://doi.org/10.1134/S1063774518010029
  43. Gurbanova O.A., Belokoneva E.L. // Crystallography Reports. 2006. V. 51. P. 577. https://doi.org/10.1134/S1063774506040067
  44. CrysAlisPro Software System, Version 1.171.37.35. Agilent Technologies UK Ltd, Oxford, UK, 2014.
  45. Sheldrick G.M. // Acta Cryst. C. 2015. V. 71. P. 3. https://doi.org/10.1107/S2053229614024218
  46. Brese N.E., O’Keeffe M. // Acta Cryst. B. 1991. V. 47. P. 192. https://doi.org/10.1107/S0108768190011041
  47. Brown I.D., Altermatt D. // Acta Cryst. B. 1985. V. 41. P. 244. https://doi.org/10.1107/S0108768185002063
  48. Groom C.R., Allen F.H. // Angew. Chem. Int. Ed. 2014. V. 53. P. 662. https://doi.org/10.1002/anie.201306438
  49. Momma K., Izumi F. // J. Appl. Cryst. 2011. V. 44. P. 1272. https://doi.org/10.1107/S0021889811038970
  50. Qian Z., Wu H., Yu H. et al. // Dalton Trans. 2020. V. 49. P. 8443. https://doi.org/10.1039/D0DT00593B
  51. Hector A.L., Henderson S.J., Levason W., Webster M. // Z. Anorg. Allg. Chem. 2002. V. 628. P. 198. https://doi.org/10.1002/1521-3749(200201)628:1<198::AID-ZAAC198>3.0.CO;2-L
  52. Yeon J., Kim S.-H., Halasyamani P.S. // J. Solid State Chem. 2009. V. 182. № 12. P. 3269. https://doi.org/10.1016/j.jssc.2009.09.021
  53. Belokoneva E.L., Reutova O.V., Dimitrova O.V. et al. // CrystEngComm. 2023. V. 25. P. 4364. https://doi.org/10.1039/D3CE00461A
  54. Chen X., Xue H., Chang X. et al. // J. Alloys Compd. 2005. V. 398. P. 173. https://doi.org/10.1016/j.jallcom.2005.01.050
  55. Hebboul Z., Galez C., Benbertal D. et al. // Crystals. 2019. V. 9. P. 464. https://doi.org/10.3390/cryst9090464
  56. Chikhaoui R., Hebboul Z., Fadla M.A. et al. // Nanomaterials. 2021. V. 11. № 12. P. 3289. http://doi.org/10.3390/nano11123289
  57. Reutova O., Belokoneva E., Volkov A., Dimitrova O. // Symmetry. 2023. V. 15. P. 1777. https://doi.org/10.3390/sym15091777

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