Diversity of fundamental building blocks [M(IO3)6] in iodate families and new trigonal polymorph of Cs2HIn(IO3)6
- Authors: Reutova O.V.1, Belokoneva E.L.1, Volkov A.S.2, Dimitrova О.V.1
-
Affiliations:
- Lomonosov Moscow State University
- Skolkovo Institute of Science and Technology
- Issue: Vol 69, No 4 (2024)
- Pages: 597-611
- Section: СТРУКТУРА НЕОРГАНИЧЕСКИХ СОЕДИНЕНИЙ
- URL: https://journals.rcsi.science/0023-4761/article/view/264363
- DOI: https://doi.org/10.31857/S0023476124040052
- EDN: https://elibrary.ru/XDNNAG
- ID: 264363
Cite item
Abstract
Crystals of new structural high-symmetry modification of Cs2HIn(IO3)6, which crystallyzes in sp. gr. R3 with parameters of unit cell a = 11.8999(4), c = 11.6513(5) Å were obtained in hydrothermal conditions. Crystal chemical comparison with triclinic modification the investigated earlier was carried out. Both structures are composed of isolated blocks [In(IO3)6]3–. The new modification belongs to the family of trigonal iodates isostructural to K2Ge(IO3)6 compound. Local symmetry of separated blocks [M(IO3)6] (M = Ge, Ti, Sn, Ga, In and other metals) are analyzed. Structural systematic of iodate families is suggested on the base of comparative crystal chemical analysis. The influence of cation composition and synthesis conditions on symmetry and topology of crystal structures as well as local symmetry of blocks on physical properties of compounds are discussed.
About the authors
O. V. Reutova
Lomonosov Moscow State University
Email: elbel@geol.msu.ru
Geological Faculty, Department of Crystallography and Crystal Chemistry
Russian Federation, MoscowE. L. Belokoneva
Lomonosov Moscow State University
Author for correspondence.
Email: elbel@geol.msu.ru
Geological Faculty, Department of Crystallography and Crystal Chemistry
Russian Federation, MoscowA. S. Volkov
Skolkovo Institute of Science and Technology
Email: elbel@geol.msu.ru
Russian Federation, Moscow
О. V. Dimitrova
Lomonosov Moscow State University
Email: elbel@geol.msu.ru
Geological Faculty, Department of Crystallography and Crystal Chemistry
Russian Federation, MoscowReferences
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