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Nitration of Phenol with Water Activated by Pulsed Hot Plasma Radiation
- Authors: Piskarev I.M.1
-
Affiliations:
- Skobeltsyn Research Institute of Nuclear Physics, Moscow State University
- Issue: Vol 57, No 4 (2023)
- Pages: 336-340
- Section: PLASMA CHEMISTRY
- URL: https://journals.rcsi.science/0023-1193/article/view/140025
- DOI: https://doi.org/10.31857/S0023119323040113
- EDN: https://elibrary.ru/QOAAFV
- ID: 140025
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Abstract
The nitration of phenol with plasma-activated water (PAW) generated by pulsed radiation of an electric spark discharge has been studied. Long-lived nitrogen-containing active species that accumulate in water during treatment are nitrous acid and the …ONOOH/ONOO− complex, which decomposes into peroxynitrite and peroxynitrous acid. Their concentration in PAW after 10 min of treatment was ~10−3 mol/L. When PAW is mixed with phenol in a 1 : 1 ratio, the identified reaction product is 4-nitrophenol. The yield
of nitration through PAW is equal to the nitration yield by the direct action of hot plasma radiation on a phenol solution.
About the authors
I. M. Piskarev
Skobeltsyn Research Institute of Nuclear Physics, Moscow State University
Author for correspondence.
Email: i.m.piskarev@gmail.com
Moscow, 119234 Russia
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