Effect of Particle Size on the Magnetostructural Transformation of a Manganese Monoarsenide-Based Phase in the ZnGeAs2–MnAs System


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We have studied the caloric and magnetic properties of alloys in the MnAs–ZnGeAs2 eutectic system. The results demonstrate that the heat effect and temperature range of the ferromagnetic-to-paramagnetic phase transformation depend on the crystallite size of manganese arsenide. Reducing the crystallite size to ≤60 nm causes the heat effect of the transformation to disappear, significantly changes the temperature range of the magnetic transition, and raises the Curie temperature of the alloy to 351 K.

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S. Marenkin

Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences; Moscow Institute of Steel and Alloys (National University of Science and Technology)

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Email: marenkin@rambler.ru
俄罗斯联邦, Leninskii pr. 31, Moscow, 119991; Leninskii pr. 4, Moscow, 119991

A. Aronov

Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences

Email: marenkin@rambler.ru
俄罗斯联邦, Leninskii pr. 31, Moscow, 119991

I. Fedorchenko

Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences

Email: marenkin@rambler.ru
俄罗斯联邦, Leninskii pr. 31, Moscow, 119991

A. Zheludkevich

Scientific–Practical Materials Research Centre (State Research and Production Association),
Belarussian Academy of Sciences

Email: marenkin@rambler.ru
白俄罗斯, ul. Brovki 19, Minsk, 220072

A. Khoroshilov

Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences

Email: marenkin@rambler.ru
俄罗斯联邦, Leninskii pr. 31, Moscow, 119991

V. Kozlov

Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences

Email: marenkin@rambler.ru
俄罗斯联邦, Leninskii pr. 29, Moscow, 119991

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