Cationic Copolymerization of Cholesterol Vinyl Ether with N-Allenylpyrrolidone: A Route to Pharmacologically Promising Oligomers
- 作者: Markova M.1, Tatarinova I.1, Tarasova O.1, Apartsin K.2, Kireeva V.2, Trofimov B.1
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隶属关系:
- Favorsky Irkutsk Institute of Chemistry, Siberian Branch, Russian Academy of Sciences
- Irkutsk Scientific Center, Siberian Branch, Russian Academy of Sciences
- 期: 卷 485, 编号 2 (2019)
- 页面: 112-115
- 栏目: Chemistry
- URL: https://journals.rcsi.science/0012-5008/article/view/154418
- DOI: https://doi.org/10.1134/S0012500819040037
- ID: 154418
如何引用文章
详细
Cationic copolymerization of cholesterol vinyl ether with N-allenylpyrrolidone yielded co-oligomers with molecular mass of 1200–2100. The polymerization of N-allenylpyrrolidone involves both 1,2- and 2,3-positions of the allenyl substituent to give four types of units as a result of prototropic isomerization of the initially formed structures. In the developed method, the composition of co-oligomers can be controlled and, hence, their hydrophilic/hydrophobic balance, solubility, and membranotropic properties can also be contolled to change the potential biological activity of the products.
作者简介
M. Markova
Favorsky Irkutsk Institute of Chemistry, Siberian Branch, Russian Academy of Sciences
Email: boris_trofimov@irioch.irk.ru
俄罗斯联邦, Irkutsk, 664033
I. Tatarinova
Favorsky Irkutsk Institute of Chemistry, Siberian Branch, Russian Academy of Sciences
Email: boris_trofimov@irioch.irk.ru
俄罗斯联邦, Irkutsk, 664033
O. Tarasova
Favorsky Irkutsk Institute of Chemistry, Siberian Branch, Russian Academy of Sciences
Email: boris_trofimov@irioch.irk.ru
俄罗斯联邦, Irkutsk, 664033
K. Apartsin
Irkutsk Scientific Center, Siberian Branch, Russian Academy of Sciences
Email: boris_trofimov@irioch.irk.ru
俄罗斯联邦, Irkutsk, 664033
V. Kireeva
Irkutsk Scientific Center, Siberian Branch, Russian Academy of Sciences
Email: boris_trofimov@irioch.irk.ru
俄罗斯联邦, Irkutsk, 664033
B. Trofimov
Favorsky Irkutsk Institute of Chemistry, Siberian Branch, Russian Academy of Sciences
编辑信件的主要联系方式.
Email: boris_trofimov@irioch.irk.ru
俄罗斯联邦, Irkutsk, 664033