


Nº 4 (2024)
Soil Fertility
Migration of Nitrate Nitrogen by Soil Profile
Resumo
In the leached low-humus medium loamy chernozem of the central zone of the Kurgan region, losses of nitrate nitrogen through leaching with precipitation down the soil profile were noted. Losses increased with the use of increased doses of nitrogen fertilizers, as well as in variants with unilateral application of nitrogen fertilizers.



Dynamics of the Humus State of Southern Chernozem with Prolonged Use of Mineral Fertilizers in the Conditions of the Steppe Volga Region
Resumo
The results of monitoring the dynamics of humus and total nitrogen of the southern chernozem in a long-term stationary experiment with the use of mineral fertilizers are presented. In the first 3 rotations of the grain-to-crop rotation, intensive mineralization of humus was noted in all variants of the experiment. In the conditions of grainsteam crop rotation, this process slowed down, and in the variant with the use of minimum doses of nitrogenphosphorus fertilizers in the 6th rotation, the accumulation of humic substances was revealed. The maximum decrease in humus content at the end of 8 rotations of crop rotation (more than 48 years) was observed in variants with the introduction of medium and high doses of nitrogenphosphorus fertilizers. The use of a minimum dose of fertilizers best compensated for the loss of humus of the southern chernozem during prolonged agricultural use. In comparison with the initial data, negative changes in the qualitative composition of humus were noted in the experiment, expressed in a decrease in the proportion of humic acids. At the end of the 8th rotation, the total nitrogen content in the soil decreased in all variants of the experiment.



Fertilizers
Effects of LongTerm Application of Mineral Fertilizers and Manure on Agrochemical Properties of Gray Forest Soil, Crops Productivity and Carbon Sequestration
Resumo
The effect of long-term application of increasing doses of mineral (from N90P75K100 to N360P300K400) and organic (cattle manure from 25 to 100 t/ha) fertilizers on the fertility of gray forest soil was studied in the micro-plot experiment. Over 9 years, 0.81–3.24 t/ha of nitrogen, 0.68–2.70 t/ha of P2O5 and 0.90–3.60 t/ha of K2O were applied with mineral fertilizers. Manure supplied 43–173 t/ha of dry matter, 16–65 t/ha of Corg, 0.85–3.41 t/ha of Ntot, 0.65–2.59 t/ha of P2O5 and 0.86–3.46 t/ha of K2O. In the yield the mineral fertilizer system exceeded the organic one by an average of 29%. At extreme doses (N360P300K400 and 100 t/ha of cattle manure) mineral fertilizers reduced crop productivity more strongly than organic fertilizers. A direct linear relationship was found between the doses of mineral and organic fertilizers and the increase in the content of available P2O5 and K2O in the soil. Application of extreme doses of fertilizers did not lead to saturation of the soil with available forms of phosphorus and potassium. Long-term application of organic fertilizers increased the soil pH(KCl) by 0.4–1.3 units and mineral fertilizers decreased it by 0.8–1.4 units. Annual application of mineral fertilizers increased soil Corg content by an average of 0.02–0.04% per year, and organic fertilizers – by 0.08–0.17% per year. Manure application at 100 t/ha over 9 years led to the saturation of the soil with organic carbon. The C : N ratio in the soil under a mineral fertilizer system was decreased, while it with the organic system was increased. An approach to calculate the carbon sequestration efficiency for the assessment of different agronomic practices is proposed. It is shown that the carbon sequestration efficiency of the organic fertilizers was 15% higher than that of the mineral fertilizers.



Effectiveness of LongActing Urea in the Growing of Spring Wheat
Resumo
spring wheat crop was studied. It was shown that encapsulated urea, in comparison with its usual form, provided an increase in the yield of spring wheat grain by 9–13%. The coating of urea granules with calcium dihydrogen phosphate contributed to a more uniform release of fertilizer nitrogen, increasing the efficiency of its use by plants by 10–13%. It was found that the effectiveness of encapsulated urea is directly dependent on the thickness of the coating granules.



Effectiveness and Duration of Action of Dolomite Screening Particles Used for Reclamation of Acidic Soils. Empirical Models of the Acidification Process of SodPodzolic Light Loamy Soil (according to Field Experience)
Resumo
In a long-term 10-variant microfield experiment based on a mediumacidic sod-podzolic light loamy soil, a comparative study of the reclamation properties of the screening of dolomite crumbs stored in dumps, without separation into fractions (SIF), particles of 5–7 and 7–10 mm in size and dolomite flour (DF) prepared from the screening of dolomite when sifting dolomite crumbs with the diameter of the holes is 0/25 mm. The experiment lasts for 14 experimental years. It has been revealed that dolomite particles of 5–7 and 7–10 mm in size are valuable calcareous material. Their use leads to the neutralization of soil acidity already in the year of liming. The higher the dose of application, the greater the reclamation effect. There were no significant differences in the effect of granules of 5–7 and 7–10 mm in size, applied in equivalent doses, on the pH value. The positive effect of liming with meliorant in the amount of 3 and 5 doses of hydrolytic acidity (Ah) did not end after 14 experimental years after reclamation and allowed to postpone the period of repeated (maintenance) liming. The positive effect of using a natural mixture of chalk fractions (SIF) in a scientifically justified dose was inferior to dolomite flour. Clustering of individual variants of the experiment was carried out according to their effect on the рHKCl value for the entire period of the experiment. Linear trends of the averaged dependencies of the acidification process for meliorant particles of various sizes over the entire period of the experiment have been developed. The mechanisms of interaction of dolomite particles with soil in the process of land reclamation are considered.



Effect of TopDressing on Chlorophyll Content in Barley Leaves and Its Relation to Grain Quality Parameters
Resumo
The effect of top-dressing at tillage phase by Polydon® Amino Start organomineral fertilizer and KAS-28 liquid mineral fertilizer on the state of the leaf pigment complex of spring barley cv. Novichok, Rodnik Prikamya and Pamyati Rodinoy and its relationship with grain quality parameters was studied under field conditions of the Kirov region of the Russian Federation in 2020–2022. Significant effect of top-dress treatments on pigment content in the flag and second leaves was revealed. The use of top-dressing with KAS-28 enhanced the association of grain quality parameters with the chlorophyll pigment content of the two upper leaves compared to the control variant. The effect of Amino Start was not uniform: some of the connections were somewhat weakened compared to the control, some intensified, and some became statistically significant. The total content of chlorophyll correlated with the content of cellulose and fat in the grain in all treatments. Compared to controls, the use of top-dress treatments altered the effectiveness of using of photoassimilates of both leaves for cellulose and fat synthesis. The obtained data indicate the possibility of predicting the content of the main parameters of spring barley’s grain quality by the content of chlorophyll pigments in flag or second leaves of plants during the flowering phase.



Influence of Different Methods of Application of Lignogumate on the Product Quality of Green Crops and Medicinal Plants
Resumo
The effectiveness of the use of lignohumate on lettuce (annual, green crop) and peppermint (perennial, medicinal plant) grown under the conditions of vegetation experiments was studied. The combination of lignohumate with the introduction of chelated fertilizers containing trace elements (zinc, copper) into peat showed a significant positive effect in obtaining high-quality plant products. The most effective was the fertilizer system, which included a combination of lignohumate with chelated forms of zinc and copper: the increase in lettuce biomass was 29–32, mint – 71–79%, the content of macroand microelements in plants became optimal.



Agroecology
Effect of Fertilizers, Seeding Rates of the Legume Component and Weather Conditions on Yield and Accumulation of Plant Residues of LupineCereal Mixtures on Grain in the Center of the NonChernozem Region
Resumo
On mediumcultivated mediumloamy sod-podzolic soils of the Central NonChernozem region, well provided with mobile phosphorus and potassium (IV–V class), the cultivation of lupine–cereal mixtures for grain with the participation of narrowleaved lupine varieties Ladny, spring wheat, barley and oats varieties of Nemchin breeding after grain precursors in a changing climate ensured grain production in an average of 5 up to 3.0–3.7 t/ha with a share of the legume component of 29–57% and the remaining dry mass of plant residues in the soil up to 6–8 t/ha with the accumulation of total nitrogen in it up to 40–60 kg/ha and biological – 12–17 kg/ha. In arid conditions (GTK = 0.80–0.92), a mixture of lupine and barley was distinguished for the better in terms of yield and weight of plant residues, and in case of waterlogging (GTK = 2.47) – mixtures with oats and spring wheat. The inclusion of liquid micronutrients of organic nature in the technological process with a stimulating effect for non-root top dressing eliminated the need for pre-sowing application of nitrogen fertilizer and, in conditions of moderate aridity, increased grain yield, depending on the composition of the mixture, to 3.9–4.9 t/ha (by 53–59%), the yield of plant residues – up to 7–11 t/ha (by 54–139%) and in them there is an accumulation of symbiotically bound nitrogen – up to 15–25 kg/ha or 5–8 times more than without their use.



Elemental Composition and Structural Features of Humic Acids from Floodplain Soils of the Selenga River Delta
Resumo
The study of the elemental composition and structure of humic acids of floodplain soils of the delta of the Selenga River (Western Transbaikalia) was carried out. The research area belongs to the delta meadowmarsh and foreststeppe region, which is an area where deposits of sandy and silty fractions are actively carried out from the entire basin. Here, soils and vegetation are natural biofilters. Depending on the bioclimatic conditions, groundwater regimes, and sediment composition, soils are formed that differ in the composition of humus and humic acids (HA). The objects of research were alluvial (meadow, meadowmarsh, meadow saline) soils of the Selenga delta, according to the classification WRB – Fluvisols. The analysis of 13C-NMR spectra of HA preparations of the studied floodplain soils made it possible to identify ranges of chemical shifts belonging to carbon atoms of various functional groups and molecular fragments. NMR spectroscopy data showed that humic acids of alluvial meadow soil are more enriched in aromatic fragments than humic acids of meadowmarsh and meadow saline soils. A slightly higher degree of aromaticity in alluvial meadow and meadowmarsh soil is associated with environmental conditions and the component composition of the precursors of humification. An increase in the proportion of aliphatic structures and a decrease in the proportion of aromatic fragments in the composition of preparations of meadow salt marsh soil make it possible to judge the simplification of the structure of humic acid. Soil moisture in combination with salinization significantly reduces the rate of transformation of soil organic matter and leads to an increase in the proportion of non-oxidized aliphatic fragments. The use of NMR spectroscopy in the study of soils has significantly expanded the understanding of its composition and structure, deepened the understanding of the mechanisms of humification and transformation of soils of various genesis.



Influence of Selenium on the Yield and Content of the Amino Acid Composition of Spring Wheat Grain under Optimal Conditions of Water Supply and during Drought
Resumo
In model experiments in soil culture, the effect of various methods of applying sodium selenite on the formation of yield and amino acid composition of grain varieties of spring wheat Zlata and Ester, depending on water supply conditions, was studied. Sodium selenite was introduced by pre-sowing seed treatment and leaf treatment of vegetative plants. The study simulated optimal water supply conditions and soil moisture deficiency during the critical period of plant growth. The role of selenium in the regulation of the production process and the formation of the amino acid composition of spring wheat grain was studied. It was found that the production process of wheat plants, both under optimal water supply and in drought conditions, depended on the method of application of selenium and the varietal characteristics of spring wheat. The results allowed us to assume that selenium activated the attenuating ability of the ear by enhancing its acceptor properties. Under these conditions, the grains were better provided with assimilates. this made it possible to form the maximum possible yield of wheat grain. In conditions of drought, during leaf treatment of plants with sodium selenite, favorable conditions were created for the formation of reproductive organs of wheat, which stimulated the restoration of the processes of assimilate outflow from the vegetative mass into the forming grains. This made it possible to influence production processes and reduce the depression of wheat crop formation. The use of selenium revealed an increase in the total content of key amino acids, which had a significant effect on the antioxidant status of plants and contributed to the realization of their adaptive potential. The positive effect of selenium on the content of a number of amino acids, including on the assimilation of methionine, was revealed, which was probably due to the synthesis of selenomethionine, since the ways of their formation are similar and it is not possible to separate them. The greatest effect of selenium was observed in the cultivation of wheat of the Zlata variety compared with wheat of the Ester variety, which was determined by varietal differences inherent genetically and the unequal protein content in the grain.



Ecotoxicology
Elemental Composition of the Leaves of the Hanging Birch (Betula pendula Roth) in the Area of the Transbaikalia Gold Deposit
Resumo
The influence of gold mining on the concentration of chemical elements in Betula pendula Roth leaves was studied. The intensity of absorption by the plant of a number of chemical elements, the possibility of using birch as a medicinal and forage plant, as well as for monitoring habitat changes were investigated. The study was conducted in plant communities located at production facilities and natural habitats in the area of the Baley gold deposit: tailings dumps of gold recovery factories (ZIF-1 and ZIF-2), a drainage landfill, a dump of the SredneGolgotai gold deposit, a tailings dump after processing monocytes, as well as in natural plant communities located in the vicinity of Baley at 13 trial sites in 2008, 2008 and 2021. The concentrations of elements in the leaves were arranged in descending order in the following sequence: Ca > Mg > P > Mn > Fe > Zn > Na > Ba > B > Cr > Ni > As > Cu > Mo > Sb > Pb > Co > Li > V > > Cd > Bi > Se > Be. With respect to the clark of terrestrial plants, the concentrations of the elements were in the following order: Cr > As > Sb > Li > Ni > Ba > Fe > Mo > Bi > Co > Zn > Mg > Clark > > Mn > P > Ca > Cu > B > Pb > Se > Cd > V > Be > Na. The absorption of As at production facilities exceeded the norm established for medicinal plant raw materials. The use of branch feed in a number of areas is not allowed due to the high level of Zn, Fe, Sb, Ni, Cr, Co, As, Cd. A relatively high coefficient of biological absorption by birch leaves Zn, Mn, P, Ca, Mg was obtained.


