Novel catalysts based on magnesium, aluminum, nickel and cobalt hydroxo salts for the carbon dioxide conversion of biogenic alcohols to hydrogen-containing gases

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Abstract

Catalysts based on alumomagnesium hydroxo salts of hydrotalcite type containing nickel and cobalt ions have been used for the first time for carbon dioxide conversion of biogenic alcohols – ethanol and isobutanol – into hydrogen-containing gases (a mixture of hydrogen and carbon monoxide). At the optimum temperatures of 800–900°C, the hydrogen yield in the conversion of ethanol reaches 77–97%, in the conversion of isobutanol – 80–89%.

About the authors

A. G. Dedov

Topchiev Institute of Petrochemical Synthesis RAS; Gubkin University

Email: al57@rambler.ru
119991 Moscow, Russian Federation; 119991 Moscow, Russian Federation

A. S. Loktev

Topchiev Institute of Petrochemical Synthesis RAS; Gubkin University

Email: al57@rambler.ru
119991 Moscow, Russian Federation; 119991 Moscow, Russian Federation

D. A. Chibrikova

Topchiev Institute of Petrochemical Synthesis RAS

Email: al57@rambler.ru
119991 Moscow, Russian Federation

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In the print version, the article was published under the DOI: 10.31857/S2686953525020058


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