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A NEW QUANTITATIVE METHOD OF EXPRESS ANALYSIS OF NATURAL RUBBER DIRECTLY IN THE ROOT OF THE RUBBER PLANT BY THE SPIN PROBE EPR METHOD
- Authors: Martirosyan L.Y.1,2, Goldberg V.M.1, Barashkova I.I.3, Kasparov V.V.1, Martirosyan Y.T.1,2, Motyakin M.V.1,3, Gaydamaka S.N.4, Varfolomeev S.D.1,4
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Affiliations:
- N.M. Emanuel Institute of Biochemical Physics of the Russian Academy of Sciences
- All-Russian Research Institute of Agricultural Biotechnology
- N.N. Semenov Federal Research Center for Chemical Physics of the Russian Academy of Sciences
- Lomonosov Moscow State University, Faculty of Chemistry, Department of Chemical Enzymology
- Issue: Vol 513, No 1 (2023)
- Pages: 43-47
- Section: CHEMISTRY
- URL: https://journals.rcsi.science/2686-9535/article/view/252491
- DOI: https://doi.org/10.31857/S2686953522600659
- EDN: https://elibrary.ru/BDLDRC
- ID: 252491
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Abstract
In this work, the phenomenon of selective sorption of a stable nitroxyl radical TEMPO on rubber particles in the powder of dried and dispersed root of kok-sagyz was discovered. This feature of the rubber-bearing root material contributed to the development of a new, highly sensitive method of quantitative analysis of rubber by the integral intensity of the EPR TEMPO signal. The main advantages of the proposed method are the speed and the ability to determine the content of rubber directly in the roots of the plant in microquantities (5–30 mg).
About the authors
L. Yu. Martirosyan
N.M. Emanuel Institute of Biochemical Physics of the Russian Academy of Sciences; All-Russian Research Institute of Agricultural Biotechnology
Author for correspondence.
Email: levon-agro@mail.ru
Russian Federation, 119334, Moscow; Russian Federation, 127550, Moscow
V. M. Goldberg
N.M. Emanuel Institute of Biochemical Physics of the Russian Academy of Sciences
Email: levon-agro@mail.ru
Russian Federation, 119334, Moscow
I. I. Barashkova
N.N. Semenov Federal Research Center for Chemical Physics of the Russian Academy of Sciences
Email: levon-agro@mail.ru
Russian Federation,
119991, Moscow
V. V. Kasparov
N.M. Emanuel Institute of Biochemical Physics of the Russian Academy of Sciences
Email: levon-agro@mail.ru
Russian Federation, 119334, Moscow
Yu. Ts. Martirosyan
N.M. Emanuel Institute of Biochemical Physics of the Russian Academy of Sciences; All-Russian Research Institute of Agricultural Biotechnology
Email: levon-agro@mail.ru
Russian Federation, 119334, Moscow; Russian Federation, 127550, Moscow
M. V. Motyakin
N.M. Emanuel Institute of Biochemical Physics of the Russian Academy of Sciences; N.N. Semenov Federal Research Center for Chemical Physics of the Russian Academy of Sciences
Email: levon-agro@mail.ru
Russian Federation, 119334, Moscow; Russian Federation,
119991, Moscow
S. N. Gaydamaka
Lomonosov Moscow State University, Faculty of Chemistry, Department of Chemical Enzymology
Email: levon-agro@mail.ru
Russian Federation,
119991, Moscow
S. D. Varfolomeev
N.M. Emanuel Institute of Biochemical Physics of the Russian Academy of Sciences; Lomonosov Moscow State University, Faculty of Chemistry, Department of Chemical Enzymology
Email: levon-agro@mail.ru
Russian Federation, 119334, Moscow; Russian Federation,
119991, Moscow
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