Y-SHAPED FLUOROPHORES BASED ON  N (2)-ARYL-1,2,3-TRIAZOLES: SYNTHESIS, THEORETICAL CALCULATIONS, OPTICAL PROPERTIES, AND APPLICATION OPPORTUNITIES FOR DETECTION OF NITROAROMATICS

I. A. Lavrinchenko; Лавринченко И. А.; T. D. Moseev; Мосеев Т. Д.; M. V. Varaksin; Вараксин М. В.; Y. A. Seleznev; Селезнев Ю. А.; L. K. Sadieva; Садиева Л. К.; G. V. Zyryanov; Зырянов Г. В.; A. N. Tsmokaluk; Цмокалюк А. Н.; V. N. Charushin; Чарушин В. Н.; O. N. Chupakhin; Чупахин О. Н.

doi:10.31857/S2686953522600702

Y-SHAPED FLUOROPHORES BASED ON N(2)-ARYL-1,2,3-TRIAZOLES: SYNTHESIS, THEORETICAL CALCULATIONS, OPTICAL PROPERTIES, AND APPLICATION OPPORTUNITIES FOR DETECTION OF NITROAROMATICS

Authors: Lavrinchenko I.A.¹, Moseev T.D.¹, Varaksin M.V.¹^,2, Seleznev Y.A.¹, Sadieva L.K.¹, Zyryanov .V.¹^,2, Tsmokaluk A.N.¹, Charushin V.N.¹^,2, Chupakhin O.N.¹^,2
Affiliations:
1. Ural Federal University
2. Institute of Organic Synthesis, Ural Branch of the Russian Academy of Sciences
Issue: Vol 512, No 1 (2023)
Pages: 21-31
Section: ХИМИЯ
URL: https://journals.rcsi.science/2686-9535/article/view/247177
DOI: https://doi.org/10.31857/S2686953522600702
EDN: https://elibrary.ru/CLZCVS
ID: 247177

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Abstract
About the authors
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Abstract

A five-stage method for the synthesis of Y-shaped push-pull fluorophores based on 2-(4′-methoxyphenyl)-1,2,3-triazole has been described. These molecules proved to possess emission in the range from 350 to 450 nm and high quantum yields QY 90–99% in solvents of various polarity. An opportunity of using the obtained compounds as chemosensors for both aromatic and aliphatic nitroanalytes at concentrations from 300 ppb has been elucidated.

Keywords

fluorophores, triazoles, chemosensors, nitroaromatic compounds

About the authors

I. A. Lavrinchenko

Ural Federal University

Email: chupakhin@ios.uran.ru
Russian Federation, 620002, Yekaterinburg

T. D. Moseev

Ural Federal University

Email: chupakhin@ios.uran.ru
Russian Federation, 620002, Yekaterinburg

M. V. Varaksin

Ural Federal University; Institute of Organic Synthesis, Ural Branch of the Russian Academy of Sciences

Author for correspondence.
Email: m.v.varaksin@urfu.ru
Russian Federation, 620002, Yekaterinburg; Russian Federation, 620990, Yekaterinburg

Y. A. Seleznev

Ural Federal University

Email: chupakhin@ios.uran.ru
Russian Federation, 620002, Yekaterinburg

L. K. Sadieva

Ural Federal University

Email: chupakhin@ios.uran.ru
Russian Federation, 620002, Yekaterinburg

G. V. Zyryanov

Ural Federal University; Institute of Organic Synthesis, Ural Branch of the Russian Academy of Sciences

Email: chupakhin@ios.uran.ru
Russian Federation, 620002, Yekaterinburg; Russian Federation, 620990, Yekaterinburg

A. N. Tsmokaluk

Ural Federal University

Email: chupakhin@ios.uran.ru
Russian Federation, 620002, Yekaterinburg

V. N. Charushin

Ural Federal University; Institute of Organic Synthesis, Ural Branch of the Russian Academy of Sciences

Email: chupakhin@ios.uran.ru
Russian Federation, 620002, Yekaterinburg; Russian Federation, 620990, Yekaterinburg

O. N. Chupakhin

Ural Federal University; Institute of Organic Synthesis, Ural Branch of the Russian Academy of Sciences

Author for correspondence.
Email: chupakhin@ios.uran.ru
Russian Federation, 620002, Yekaterinburg; Russian Federation, 620990, Yekaterinburg

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