New Fluorescent Materials Based on Polysiloxanes and Boron Bis(β-diketonates)

E. E. Kim; Ким Э. Е.; T. M. Il’ina; Ильина Т. М.; Yu. N. Kononevich; Кононевич Ю. Н.; D. S. Ionov; Ионов Д. С.; D. A. Khanin; Ханин Д. А.; G. G. Nikiforova; Никифорова Г. Г.; A. M. Muzafarov; Музафаров А. М.

doi:10.31857/S2308114723700371

New Fluorescent Materials Based on Polysiloxanes and Boron Bis(β-diketonates)

Authors: Kim E.E.¹, Il’ina T.M.¹^,2, Kononevich Y.N.¹, Ionov D.S.³, Khanin D.A.¹, Nikiforova G.G.¹, Muzafarov A.M.¹^,4
Affiliations:
1. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences
2. Mendeleev University of Chemical Technology of Russia
3. Photochemistry Center, Federal National Research Center “Crystallography and Photonics,” Russian Academy of Sciences
4. Enikolopov Institute of Synthetic Polymer Materials, Russian Academy of Sciences
Issue: Vol 65, No 2 (2023)
Pages: 284-294
Section:
URL: https://journals.rcsi.science/2308-1147/article/view/232928
DOI: https://doi.org/10.31857/S2308114723700371
EDN: https://elibrary.ru/GCBIOS
ID: 232928

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Abstract
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Abstract

Crosslinked polysiloxanes with boron bis(dibenzoylmethanate) complexes used as crosslink junctions of polymer networks are first synthesized, and their physicochemical, mechanical, thermal, and fluorescent properties are studied. It is shown that the polymers under study feature the elastic behavior, possess high thermal and thermo-oxidative stability, and exhibit intense fluorescence in a wide wavelength range (400‒700 nm).

About the authors

E. E. Kim

Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences

Email: kononevich.yuriy@gmail.com
119334, Moscow, Russia

T. M. Il’ina

Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences; Mendeleev University of Chemical Technology of Russia

Email: kononevich.yuriy@gmail.com
119334, Moscow, Russia; 125047, Moscow, Russia

Yu. N. Kononevich

Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences

Email: kononevich.yuriy@gmail.com
119334, Moscow, Russia

D. S. Ionov

Photochemistry Center, Federal National Research Center “Crystallography and Photonics,” Russian Academy of Sciences

Email: kononevich.yuriy@gmail.com
119421, Moscow, Russia

D. A. Khanin

Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences

Email: kononevich.yuriy@gmail.com
119334, Moscow, Russia

G. G. Nikiforova

Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences

Email: kononevich.yuriy@gmail.com
119334, Moscow, Russia

A. M. Muzafarov

Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences; Enikolopov Institute of Synthetic Polymer Materials, Russian Academy of Sciences

Author for correspondence.
Email: kononevich.yuriy@gmail.com
119334, Moscow, Russia; 117393, Moscow, Russia

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