Preparation of Nonwoven Carbon Materials from Fabrics Based on Flax Cellulose and Viscose Fibers
- 作者: Makarov I.1, Smyslov A.2, Chernenko D.1, Vinogradov M.1, Legkov S.1, Levin I.1, Arkharova N.3, Kulichikhin V.1
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隶属关系:
- Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences
- LLC Linum
- Shubnikov Institute of Crystallography, Federal Research Center “Crystallography and Photonics,” Russian Academy of Sciences
- 期: 卷 65, 编号 3 (2023)
- 页面: 175-185
- 栏目: СТРУКТУРА И СВОЙСТВА
- URL: https://journals.rcsi.science/2308-1120/article/view/135321
- DOI: https://doi.org/10.31857/S2308112023700530
- EDN: https://elibrary.ru/MLHCHY
- ID: 135321
如何引用文章
详细
A method for obtaining nonwoven carbon materials by the staged heat treatment of cellulose felt is developed. Fabrics produced from fibrous flax cellulose and viscose fibers by needle punching are used as nonwoven precursors. To obtain carbon fabric precursors the optimum ratios of components are chosen from the data on the formation of nonwoven fabrics and the thermal analysis of various blend formulations. It is shown that the content of flax fibers in the system should be at least 50%. Viscose fibers play the role of a reinforcing material and so far cannot be fully excluded from the system. With an increase in the content of flax cellulose the value of carbon yield grows. The mechanical properties of the carbon felt are provided by the physical network of friction and dispersion contacts between individual fibers. Upon heat treatment of the composite nonwoven material, the morphological features of precursor fibers remain unchanged. The interplanar distances of carbon layers in the carbon material are calculated using X-ray diffraction analysis and transmission electron microscopy. The fraction of carbon upon heat treatment to 1700°С is at least 90%, and after graphitization to 2400°С the purity of the product is above 99%. The maximum values of carbon yield at this temperature may be as high as 25‒27%. The coefficients of thermal conductivity of the carbon felt are measured, and the values obtained are 30% lower than the corresponding parameters of carbon fabrics.
作者简介
I. Makarov
Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences
Email: makarov@ips.ac.ru
119991, Moscow, Russia
A. Smyslov
LLC Linum
Email: makarov@ips.ac.ru
454100, Chelyabinsk, Russia
D. Chernenko
Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences
Email: makarov@ips.ac.ru
119991, Moscow, Russia
M. Vinogradov
Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences
Email: makarov@ips.ac.ru
119991, Moscow, Russia
S. Legkov
Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences
Email: makarov@ips.ac.ru
119991, Moscow, Russia
I. Levin
Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences
Email: makarov@ips.ac.ru
119991, Moscow, Russia
N. Arkharova
Shubnikov Institute of Crystallography, Federal Research Center “Crystallography and Photonics,” Russian Academy of Sciences
Email: makarov@ips.ac.ru
119333, Moscow, Russia
V. Kulichikhin
Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences
编辑信件的主要联系方式.
Email: makarov@ips.ac.ru
119991, Moscow, Russia
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