Modeling of the Membrane Gas Separation Process of CO2 Decomposition Products with the Production of CO and O2 Concentrates

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Abstract

Carbonylation and oxidative carbonylation processes require the production of a concentrate of carbon monoxide or its mixture with oxygen. Such concentrates can be produced by plasma-chemical decomposition of CO2 into CO and O2. Given the low conversion of such processes, there is a need to develop separation schemes for the 73% mol. CO2/18% mol. CO/9% mol. O2 mixture to produce concentrates that are practical to use. This article proposes a conceptual scheme for separating CO2 decomposition products using membrane gas separation technology with polysulfone hollow fiber gas separation membranes (PSF). For the first time, data on the transfer of CO, CO2, and O2 through PSF membranes in a ternary mixture were obtained for the simulation. Calculations show that using PSF membranes with a total area of 5.28 m2 when processing 1 m3 (STP)/h of the CO2/CO/O2 mixture, 93.9% CO2 with a concentration of 93.6 % mol. and extract 68.5% CO with a concentration of 85% mol.

About the authors

E. A. Grushevenko

A.V. Topchiev Institute of Petrochemical Synthesis RAS; Lomonosov Moscow State University

Email: evgrushevenko@ips.ac.ru
Department of Chemistry Moscow, Russian Federation; Moscow, Russian Federation

D. V. Miroshnichenko

A.V. Topchiev Institute of Petrochemical Synthesis RAS

Moscow, Russian Federation

L. G. Gasanova

A.V. Topchiev Institute of Petrochemical Synthesis RAS

Moscow, Russian Federation

D. N. Matveev

A.V. Topchiev Institute of Petrochemical Synthesis RAS

Moscow, Russian Federation

M. G. Shalygin

A.V. Topchiev Institute of Petrochemical Synthesis RAS

Moscow, Russian Federation

I. L. Borisov

A.V. Topchiev Institute of Petrochemical Synthesis RAS

Moscow, Russian Federation

A. L. Maksimov

Lomonosov Moscow State University

Department of Chemistry Moscow, Russian Federation

S. D. Bazhenov

A.V. Topchiev Institute of Petrochemical Synthesis RAS

Moscow, Russian Federation

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