Membrane Gas Separation of CO-containing Mixtures: Current State and Prospects

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Abstract

The review presents the current state of research in the field of membrane separation of gas mixtures containing carbon monoxide (CO). The main advantages of the membrane method in comparison with traditional approaches such as cryogenic distillation and adsorption are considered, as well as its key limitations. The literature data on the transport properties and selectivity of various classes of membrane materials for the separation of practically important mixtures of CO/H₂, CO/CH₄, CO/CO₂, CO/N₂ and CO/O₂ are summarized. The main research directions, including the use of polymer, carbon, inorganic membranes, as well as membranes based on ionic liquids, are considered. The main difficulties limiting the industrial application of membrane technologies have also been identified, and promising directions for their development have been outlined in order to increase the efficiency of CO-containing mixtures separation processes.

About the authors

D. N. Matveev

Topchiev Institute of Petrochemical Synthesis, RAS

Email: dmatveev@ips.ac.ru
Leninsky prosp., 29, Moscow, 119991, Russia

E. A. Grushevenko

Topchiev Institute of Petrochemical Synthesis, RAS; Department of Chemistry, Lomonosov Moscow State University

Leninsky prosp., 29, Moscow, 119991, Russia; Leninskie Gory, Moscow, 119991, Russia

T. S. Anokhina

Topchiev Institute of Petrochemical Synthesis, RAS

Leninsky prosp., 29, Moscow, 119991, Russia

A. V. Volkov

Topchiev Institute of Petrochemical Synthesis, RAS

Leninsky prosp., 29, Moscow, 119991, Russia

A. L. Maksimov

Department of Chemistry, Lomonosov Moscow State University

Leninskie Gory, Moscow, 119991, Russia

I. L. Borisov

Topchiev Institute of Petrochemical Synthesis, RAS

Leninsky prosp., 29, Moscow, 119991, Russia

S. D. Bazhenov

Topchiev Institute of Petrochemical Synthesis, RAS

Leninsky prosp., 29, Moscow, 119991, Russia

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