Properties of Polysulphones Synthetized for Forming of Porous Hollow-Fiber Membranes

I. L. Borisov; Борисов И. Л.; D. N. Matveev; Матвеев Д. Н.; T. S. Anokhina; Анохина Т. С.; K. T. Shakhmurzova; Шахмурзова К. Т.; A. A. Zhansitov; Жанситов А. А.; A. L. Slonov; Слонов А. Л.; Zh. I. Kurdanova; Курданова Ж. И.; S. Yu. Khashirova; Хаширова С. Ю.; V. V. Volkov; Волков В. В.

doi:10.31857/S2218117223030021

Properties of Polysulphones Synthetized for Forming of Porous Hollow-Fiber Membranes

Authors: Borisov I.L.¹, Matveev D.N.¹, Anokhina T.S.¹, Shakhmurzova K.T.², Zhansitov A.A.², Slonov A.L.², Kurdanova Z.I.², Khashirova S.Y.¹^,2, Volkov V.V.¹
Affiliations:
1. Topchiev Institute of Petrochemical Synthesis, RAS
2. Kabardino-Balkarian State University named after H.M. Berbekov
Issue: Vol 13, No 3 (2023)
Pages: 248-256
Section: Articles
URL: https://journals.rcsi.science/2218-1172/article/view/138012
DOI: https://doi.org/10.31857/S2218117223030021
EDN: https://elibrary.ru/DTXGUD
ID: 138012

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Abstract
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Abstract

For the first time, for the problem of hollow fiber membranes spinning, polysulfones in a wide range of molecular weights (42 000–184 000 g/mol) were synthesized in such aprotic dipolar solvents as dimethylacetamide, N-methyl-2-pyrollidone, and dimethyl sulfoxide. The dependence of the thermal and mechanical properties of polysulfones on molecular weight characteristics has been studied. A comparison of the mechanical properties of the synthesized PSF, commercial PSF Ultrason S 6010 (BASF, Germany) and PSF-150 (JSC Institute of Plastics, Russia) showed that the synthesized polymers are not inferior to commercial analogues. Some synthesized polymers surpass commercial PSF in terms of elasticity and strength modulus. Based on the study of the spinning solutions dynamic viscosity, promising PSF samples were selected for the formation of porous hollow fiber supports. It was found that hollow-fiber porous support from a PSF sample with a molecular weight of 110 000 g/mol have a high nitrogen permeability of 47.5 m³/m² · h · bar. Such supports are promising for casting highly permeable composite membranes with a thin selective layer.

Keywords

polysulfone, molecular weight, hollow fiber membranes, thermal properties

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