Elecrtochemical Investigation of Heterogeneous Cation-Exchange Membranes Modified by Polyanilin in Solutions of Monovalent and Divalent Cations

M. A. Brovkina; Бровкина М. А.; N. A. Kutenko; Кутенко Н. А.; N. V. Loza; Лоза Н. В.

doi:10.31857/S2218117223030033

Elecrtochemical Investigation of Heterogeneous Cation-Exchange Membranes Modified by Polyanilin in Solutions of Monovalent and Divalent Cations

Authors: Brovkina M.A.¹, Kutenko N.A.¹, Loza N.V.¹
Affiliations:
1. Kuban State University
Issue: Vol 13, No 3 (2023)
Pages: 205-220
Section: Articles
URL: https://journals.rcsi.science/2218-1172/article/view/138006
DOI: https://doi.org/10.31857/S2218117223030033
EDN: https://elibrary.ru/DUAWRY
ID: 138006

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Abstract
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Abstract

A series of composite ion-exchange membranes based on a heterogeneous cation-exchange MK-40 membrane and polyaniline was obtained under the conditions of electrodiffusion of a monomer and an oxidizing agent. The process of polyaniline synthesis on the membrane surface was accompanied by the registration of chronopotentiograms and the pH of the solution leaving the desalination compartment. The initial MK-40 cation-exchange membrane and the composites based on it were studied by voltammetry and chronopotentiometry in NaCl, CaCl₂, and MgCl₂ solutions in the same electrodialysis flow cell in which the composites were obtained. To calculate the transport numbers of counterions in membranes in CaCl₂ and MgCl₂ solutions by the chronopotentiometric method, the apparent fraction of the conducting membrane surface in the NaCl solution was calculated based on experimental data on the potentiometric transport numbers of counterions in the membrane. The conditions for the synthesis of polyaniline on the surface of a heterogeneous MK-40 membrane, leading to the preparation of samples with selectivity to singly charged ions, are revealed.

Keywords

ion-exchange membrane, polyaniline, current–voltage characteristic, chronopotentiogram, transport numbers

References

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