Adsorption of Sodium Oleyl Sarcosinate on Zinc and Its Passivating Action in Neutral Aqueous Solution


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The adsorption, protective, and passivating effect of some sodium salts of higher carboxylates and sodium dioctyl phosphate on zinc in borate buffer solution with pH of 7.4 were studied. It has been shown that sodium oleyl sarcosinate has the best protective and adsorption properties. It has been established that the adsorption of oleyl sarcosinate on zinc is multilayer, which contributes to its best protection under anodic dissolution and in a humid atmosphere with periodic condensation of moisture on the samples. Treatment of Zn in aqueous solutions of inhibitors increases the time until the appearance of the first corrosion lesions on it under conditions of humid atmosphere 2.5–4.5 times.

作者简介

M. Agafonkina

Frumkin Institute of Physical Chemistry and Electrochemistry,
Russian Academy of Sciences

Email: kuznetsov@ipc.rssi.ru
俄罗斯联邦, Moscow, 119071

A. Semiletov

Frumkin Institute of Physical Chemistry and Electrochemistry,
Russian Academy of Sciences

Email: kuznetsov@ipc.rssi.ru
俄罗斯联邦, Moscow, 119071

Yu. Kuznetsov

Frumkin Institute of Physical Chemistry and Electrochemistry,
Russian Academy of Sciences

编辑信件的主要联系方式.
Email: kuznetsov@ipc.rssi.ru
俄罗斯联邦, Moscow, 119071

N. Andreeva

Frumkin Institute of Physical Chemistry and Electrochemistry,
Russian Academy of Sciences

Email: kuznetsov@ipc.rssi.ru
俄罗斯联邦, Moscow, 119071

A. Chirkunov

Frumkin Institute of Physical Chemistry and Electrochemistry,
Russian Academy of Sciences

Email: kuznetsov@ipc.rssi.ru
俄罗斯联邦, Moscow, 119071

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