Preparing and studying Pt/WO3/ZrO2 catalysts for the isomerization of n-heptane


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The effect of the temperature of WO3/ZrO2 support calcination in the range of 700–1000°C on the phase composition, acid, and catalytic properties of Pt/WO3/ZrO2 catalysts is studied. Using ammonia TPD, it is found that calcination in the temperature range of 850–950°C results in the formation of strong acid sites that increase the yield of the target products of the reaction of n-heptane isomerization: high octane di- and trimethylsubstituted isomers. DRIFT is used to determine the role of catalyst calcination in an air flow plays in the formation of charged platinum atoms, which results in higher catalyst activity.

作者简介

M. Smolikov

Institute of Hydrocarbons Processing; Omsk State Technical University

编辑信件的主要联系方式.
Email: smolikov@ihcp.ru
俄罗斯联邦, Omsk, 644040; Omsk, 644050

V. Shkurenok

Institute of Hydrocarbons Processing

Email: smolikov@ihcp.ru
俄罗斯联邦, Omsk, 644040

S. Yablokova

Institute of Hydrocarbons Processing

Email: smolikov@ihcp.ru
俄罗斯联邦, Omsk, 644040

D. Kir’yanov

Institute of Hydrocarbons Processing

Email: smolikov@ihcp.ru
俄罗斯联邦, Omsk, 644040

E. Paukshtis

Boreskov Institute of Catalysis

Email: smolikov@ihcp.ru
俄罗斯联邦, Novosibirsk, 630090

N. Leont’eva

Institute of Hydrocarbons Processing

Email: smolikov@ihcp.ru
俄罗斯联邦, Omsk, 644040

A. Belyi

Institute of Hydrocarbons Processing; Omsk State Technical University

Email: smolikov@ihcp.ru
俄罗斯联邦, Omsk, 644040; Omsk, 644050

V. Drozdov

Institute of Hydrocarbons Processing; Omsk Scientific Center

Email: smolikov@ihcp.ru
俄罗斯联邦, Omsk, 644040; Omsk, 644024

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