Preparing and studying Pt/WO3/ZrO2 catalysts for the isomerization of n-heptane
- 作者: Smolikov M.D.1,2, Shkurenok V.A.1, Yablokova S.S.1, Kir’yanov D.I.1, Paukshtis E.A.3, Leont’eva N.N.1, Belyi A.S.1,2, Drozdov V.A.1,4
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隶属关系:
- Institute of Hydrocarbons Processing
- Omsk State Technical University
- Boreskov Institute of Catalysis
- Omsk Scientific Center
- 期: 卷 9, 编号 1 (2017)
- 页面: 54-61
- 栏目: Domestic Catalysts
- URL: https://journals.rcsi.science/2070-0504/article/view/202437
- DOI: https://doi.org/10.1134/S2070050417010135
- ID: 202437
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详细
The effect of the temperature of WO3/ZrO2 support calcination in the range of 700–1000°C on the phase composition, acid, and catalytic properties of Pt/WO3/ZrO2 catalysts is studied. Using ammonia TPD, it is found that calcination in the temperature range of 850–950°C results in the formation of strong acid sites that increase the yield of the target products of the reaction of n-heptane isomerization: high octane di- and trimethylsubstituted isomers. DRIFT is used to determine the role of catalyst calcination in an air flow plays in the formation of charged platinum atoms, which results in higher catalyst activity.
作者简介
M. Smolikov
Institute of Hydrocarbons Processing; Omsk State Technical University
编辑信件的主要联系方式.
Email: smolikov@ihcp.ru
俄罗斯联邦, Omsk, 644040; Omsk, 644050
V. Shkurenok
Institute of Hydrocarbons Processing
Email: smolikov@ihcp.ru
俄罗斯联邦, Omsk, 644040
S. Yablokova
Institute of Hydrocarbons Processing
Email: smolikov@ihcp.ru
俄罗斯联邦, Omsk, 644040
D. Kir’yanov
Institute of Hydrocarbons Processing
Email: smolikov@ihcp.ru
俄罗斯联邦, Omsk, 644040
E. Paukshtis
Boreskov Institute of Catalysis
Email: smolikov@ihcp.ru
俄罗斯联邦, Novosibirsk, 630090
N. Leont’eva
Institute of Hydrocarbons Processing
Email: smolikov@ihcp.ru
俄罗斯联邦, Omsk, 644040
A. Belyi
Institute of Hydrocarbons Processing; Omsk State Technical University
Email: smolikov@ihcp.ru
俄罗斯联邦, Omsk, 644040; Omsk, 644050
V. Drozdov
Institute of Hydrocarbons Processing; Omsk Scientific Center
Email: smolikov@ihcp.ru
俄罗斯联邦, Omsk, 644040; Omsk, 644024
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