Possible Mechanism of Thermal Reduction of Graphite Oxide
- Авторы: Gridnev A.A.1, Gudkov M.V.1, Bekhli L.S.1, Mel’nikov V.P.1
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Учреждения:
- Semenov Institute of Chemical Physics
- Выпуск: Том 12, № 6 (2018)
- Страницы: 1008-1016
- Раздел: Kinetics and Mechanism of Chemical Reactions. Catalysis
- URL: https://journals.rcsi.science/1990-7931/article/view/201282
- DOI: https://doi.org/10.1134/S1990793118060155
- ID: 201282
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Аннотация
A mechanism for the thermal reduction of graphite oxide is proposed. The process begins with the homolysis of the C–C bond in the basal plane of graphite oxide with subsequent reactions of isomerization of the formed radicals. The formation of both CO and a significant amount of CO2 was explained to occur via the cleavage of 1,3-dioxetane, which forms by the disproportionation and recombination of free radicals.
Об авторах
A. Gridnev
Semenov Institute of Chemical Physics
Автор, ответственный за переписку.
Email: 99gridnev@gmail.com
Россия, Moscow, 119991
M. Gudkov
Semenov Institute of Chemical Physics
Email: 99gridnev@gmail.com
Россия, Moscow, 119991
L. Bekhli
Semenov Institute of Chemical Physics
Email: 99gridnev@gmail.com
Россия, Moscow, 119991
V. Mel’nikov
Semenov Institute of Chemical Physics
Email: 99gridnev@gmail.com
Россия, Moscow, 119991
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