Possible Mechanism of Thermal Reduction of Graphite Oxide
- Авторлар: Gridnev A.A.1, Gudkov M.V.1, Bekhli L.S.1, Mel’nikov V.P.1
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Мекемелер:
- Semenov Institute of Chemical Physics
- Шығарылым: Том 12, № 6 (2018)
- Беттер: 1008-1016
- Бөлім: Kinetics and Mechanism of Chemical Reactions. Catalysis
- URL: https://journals.rcsi.science/1990-7931/article/view/201282
- DOI: https://doi.org/10.1134/S1990793118060155
- ID: 201282
Дәйексөз келтіру
Аннотация
A mechanism for the thermal reduction of graphite oxide is proposed. The process begins with the homolysis of the C–C bond in the basal plane of graphite oxide with subsequent reactions of isomerization of the formed radicals. The formation of both CO and a significant amount of CO2 was explained to occur via the cleavage of 1,3-dioxetane, which forms by the disproportionation and recombination of free radicals.
Авторлар туралы
A. Gridnev
Semenov Institute of Chemical Physics
Хат алмасуға жауапты Автор.
Email: 99gridnev@gmail.com
Ресей, Moscow, 119991
M. Gudkov
Semenov Institute of Chemical Physics
Email: 99gridnev@gmail.com
Ресей, Moscow, 119991
L. Bekhli
Semenov Institute of Chemical Physics
Email: 99gridnev@gmail.com
Ресей, Moscow, 119991
V. Mel’nikov
Semenov Institute of Chemical Physics
Email: 99gridnev@gmail.com
Ресей, Moscow, 119991
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