Possible Mechanism of Thermal Reduction of Graphite Oxide

A. A. Gridnev; M. V. Gudkov; L. S. Bekhli; V. P. Mel’nikov

doi:10.1134/S1990793118060155

Possible Mechanism of Thermal Reduction of Graphite Oxide

作者: Gridnev A.A.¹, Gudkov M.V.¹, Bekhli L.S.¹, Mel’nikov V.P.¹
隶属关系:
1. Semenov Institute of Chemical Physics
期: 卷 12, 编号 6 (2018)
页面: 1008-1016
栏目: Kinetics and Mechanism of Chemical Reactions. Catalysis
URL: https://journals.rcsi.science/1990-7931/article/view/201282
DOI: https://doi.org/10.1134/S1990793118060155
ID: 201282

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A mechanism for the thermal reduction of graphite oxide is proposed. The process begins with the homolysis of the C–C bond in the basal plane of graphite oxide with subsequent reactions of isomerization of the formed radicals. The formation of both CO and a significant amount of CO₂ was explained to occur via the cleavage of 1,3-dioxetane, which forms by the disproportionation and recombination of free radicals.