Мақаланы E-mail арқылы жіберу Synthesis, characterization and gelation mechanism of L-phenylalanine-based dihydrazide derivative as excellent gelator
- Авторлар: Yu Y.1, Chu N.1, Li X.Y.1, Song N.1, Liu C.1, Yu L.N.1, Li B.1, Wang C.1, Zhao Z.G.1, Zhao Y.N.1, Sheng Y.G.1, Wang C.S.1
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Мекемелер:
- The Key Laboratory of the Inorganic Molecule-Based Chemistry of Liaoning Province and Laboratory of Coordination Chemistry
- Шығарылым: Том 11, № 1 (2017)
- Беттер: 121-128
- Бөлім: Kinetics and Mechanism of Chemical Reactions. Catalysis
- URL: https://journals.rcsi.science/1990-7931/article/view/199002
- DOI: https://doi.org/10.1134/S1990793117010134
- ID: 199002
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Аннотация
A new organogelator, L-phenylalanine dihydrazide derivative (BOC-Phe-HdHz) has been designed, synthesized and characterized. In addition, the gelling behaviors of BOC-Phe-HdHz were studied. The organogelator has been shown to be capable of forming stable thermoreversible organogels in various organic solvents at extremely low concentrations (<3 wt %). The gel–sol phase transition temperatures (TGS) were determined as a function of gelator concentration and the corresponding enthalpies (ΔHg) were extracted. SEM revealed that the gelator self-assembled into different supramolecular network structures in different gels. FT-IR confirmed that hydrogen bonding and hydrophobic interaction were the driving forces for the supramolecular assembly process. XRD was measured in three different states of the gelator: solid powder, gel and xerogel. In addition, XRD and molecular modeling studies have been carried out and provided more information of the possible packing modes for the formation of organogelator aggregates.
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Авторлар туралы
Y. Yu
The Key Laboratory of the Inorganic Molecule-Based Chemistry of Liaoning Province and Laboratory of Coordination Chemistry
Email: wchsh18@163.com
ҚХР, Shenyang, 110142
N. Chu
The Key Laboratory of the Inorganic Molecule-Based Chemistry of Liaoning Province and Laboratory of Coordination Chemistry
Email: wchsh18@163.com
ҚХР, Shenyang, 110142
X. Li
The Key Laboratory of the Inorganic Molecule-Based Chemistry of Liaoning Province and Laboratory of Coordination Chemistry
Email: wchsh18@163.com
ҚХР, Shenyang, 110142
N. Song
The Key Laboratory of the Inorganic Molecule-Based Chemistry of Liaoning Province and Laboratory of Coordination Chemistry
Email: wchsh18@163.com
ҚХР, Shenyang, 110142
C. Liu
The Key Laboratory of the Inorganic Molecule-Based Chemistry of Liaoning Province and Laboratory of Coordination Chemistry
Email: wchsh18@163.com
ҚХР, Shenyang, 110142
L. Yu
The Key Laboratory of the Inorganic Molecule-Based Chemistry of Liaoning Province and Laboratory of Coordination Chemistry
Email: wchsh18@163.com
ҚХР, Shenyang, 110142
B. Li
The Key Laboratory of the Inorganic Molecule-Based Chemistry of Liaoning Province and Laboratory of Coordination Chemistry
Email: wchsh18@163.com
ҚХР, Shenyang, 110142
C. Wang
The Key Laboratory of the Inorganic Molecule-Based Chemistry of Liaoning Province and Laboratory of Coordination Chemistry
Email: wchsh18@163.com
ҚХР, Shenyang, 110142
Z. Zhao
The Key Laboratory of the Inorganic Molecule-Based Chemistry of Liaoning Province and Laboratory of Coordination Chemistry
Email: wchsh18@163.com
ҚХР, Shenyang, 110142
Y. Zhao
The Key Laboratory of the Inorganic Molecule-Based Chemistry of Liaoning Province and Laboratory of Coordination Chemistry
Email: wchsh18@163.com
ҚХР, Shenyang, 110142
Y. Sheng
The Key Laboratory of the Inorganic Molecule-Based Chemistry of Liaoning Province and Laboratory of Coordination Chemistry
Хат алмасуға жауапты Автор.
Email: yygara@qq.com
ҚХР, Shenyang, 110142
C. Wang
The Key Laboratory of the Inorganic Molecule-Based Chemistry of Liaoning Province and Laboratory of Coordination Chemistry
Хат алмасуға жауапты Автор.
Email: wchsh18@163.com
ҚХР, Shenyang, 110142
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