Enviar artigo por via de e-mail Synthesis, characterization and gelation mechanism of L-phenylalanine-based dihydrazide derivative as excellent gelator
- Autores: Yu Y.1, Chu N.1, Li X.Y.1, Song N.1, Liu C.1, Yu L.N.1, Li B.1, Wang C.1, Zhao Z.G.1, Zhao Y.N.1, Sheng Y.G.1, Wang C.S.1
-
Afiliações:
- The Key Laboratory of the Inorganic Molecule-Based Chemistry of Liaoning Province and Laboratory of Coordination Chemistry
- Edição: Volume 11, Nº 1 (2017)
- Páginas: 121-128
- Seção: Kinetics and Mechanism of Chemical Reactions. Catalysis
- URL: https://journals.rcsi.science/1990-7931/article/view/199002
- DOI: https://doi.org/10.1134/S1990793117010134
- ID: 199002
Citar
Acesso aberto
Acesso está concedido
Somente assinantes
Resumo
A new organogelator, L-phenylalanine dihydrazide derivative (BOC-Phe-HdHz) has been designed, synthesized and characterized. In addition, the gelling behaviors of BOC-Phe-HdHz were studied. The organogelator has been shown to be capable of forming stable thermoreversible organogels in various organic solvents at extremely low concentrations (<3 wt %). The gel–sol phase transition temperatures (TGS) were determined as a function of gelator concentration and the corresponding enthalpies (ΔHg) were extracted. SEM revealed that the gelator self-assembled into different supramolecular network structures in different gels. FT-IR confirmed that hydrogen bonding and hydrophobic interaction were the driving forces for the supramolecular assembly process. XRD was measured in three different states of the gelator: solid powder, gel and xerogel. In addition, XRD and molecular modeling studies have been carried out and provided more information of the possible packing modes for the formation of organogelator aggregates.
Palavras-chave
Sobre autores
Y. Yu
The Key Laboratory of the Inorganic Molecule-Based Chemistry of Liaoning Province and Laboratory of Coordination Chemistry
Email: wchsh18@163.com
República Popular da China, Shenyang, 110142
N. Chu
The Key Laboratory of the Inorganic Molecule-Based Chemistry of Liaoning Province and Laboratory of Coordination Chemistry
Email: wchsh18@163.com
República Popular da China, Shenyang, 110142
X. Li
The Key Laboratory of the Inorganic Molecule-Based Chemistry of Liaoning Province and Laboratory of Coordination Chemistry
Email: wchsh18@163.com
República Popular da China, Shenyang, 110142
N. Song
The Key Laboratory of the Inorganic Molecule-Based Chemistry of Liaoning Province and Laboratory of Coordination Chemistry
Email: wchsh18@163.com
República Popular da China, Shenyang, 110142
C. Liu
The Key Laboratory of the Inorganic Molecule-Based Chemistry of Liaoning Province and Laboratory of Coordination Chemistry
Email: wchsh18@163.com
República Popular da China, Shenyang, 110142
L. Yu
The Key Laboratory of the Inorganic Molecule-Based Chemistry of Liaoning Province and Laboratory of Coordination Chemistry
Email: wchsh18@163.com
República Popular da China, Shenyang, 110142
B. Li
The Key Laboratory of the Inorganic Molecule-Based Chemistry of Liaoning Province and Laboratory of Coordination Chemistry
Email: wchsh18@163.com
República Popular da China, Shenyang, 110142
C. Wang
The Key Laboratory of the Inorganic Molecule-Based Chemistry of Liaoning Province and Laboratory of Coordination Chemistry
Email: wchsh18@163.com
República Popular da China, Shenyang, 110142
Z. Zhao
The Key Laboratory of the Inorganic Molecule-Based Chemistry of Liaoning Province and Laboratory of Coordination Chemistry
Email: wchsh18@163.com
República Popular da China, Shenyang, 110142
Y. Zhao
The Key Laboratory of the Inorganic Molecule-Based Chemistry of Liaoning Province and Laboratory of Coordination Chemistry
Email: wchsh18@163.com
República Popular da China, Shenyang, 110142
Y. Sheng
The Key Laboratory of the Inorganic Molecule-Based Chemistry of Liaoning Province and Laboratory of Coordination Chemistry
Autor responsável pela correspondência
Email: yygara@qq.com
República Popular da China, Shenyang, 110142
C. Wang
The Key Laboratory of the Inorganic Molecule-Based Chemistry of Liaoning Province and Laboratory of Coordination Chemistry
Autor responsável pela correspondência
Email: wchsh18@163.com
República Popular da China, Shenyang, 110142
Arquivos suplementares
