Thermal Expansion and Phase Transitions in Na3H(SO4)2 Sulfate in the Low-Temperature Range


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The thermal behavior of Na3H(SO4)2 is studied in the temperature range –180...220°C in a pre-vacuum. At 180°C, the compound decomposed into a mixture of phases: Na2SO4 (Cmcm), Na2SO4 (P63/mmc), Na2SO4 (Fddd), and Na2S2O7. The maximal thermal expansion was observed near the α33 axis. The anisotropy of thermal expansion sharply decreased together with the increase in temperature.

Sobre autores

N. Dmitrieva

Grebenshchikov Institute of Silicate Chemistry, Russian Academy of Sciences

Email: rimma_bubnova@mail.ru
Rússia, St. Petersburg, 199034

R. Bubnova

Grebenshchikov Institute of Silicate Chemistry, Russian Academy of Sciences; St. Petersburg State University

Autor responsável pela correspondência
Email: rimma_bubnova@mail.ru
Rússia, St. Petersburg, 199034; St. Petersburg, 199034

S. Filatov

Grebenshchikov Institute of Silicate Chemistry, Russian Academy of Sciences

Email: rimma_bubnova@mail.ru
Rússia, St. Petersburg, 199034

A. Shablinskii

Grebenshchikov Institute of Silicate Chemistry, Russian Academy of Sciences; St. Petersburg State University

Email: rimma_bubnova@mail.ru
Rússia, St. Petersburg, 199034; St. Petersburg, 199034

M. Krzhizhanovskaya

St. Petersburg State University

Email: rimma_bubnova@mail.ru
Rússia, St. Petersburg, 199034

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