Thermal Expansion and Phase Transitions in Na3H(SO4)2 Sulfate in the Low-Temperature Range
- 作者: Dmitrieva N.1, Bubnova R.1,2, Filatov S.1, Shablinskii A.1,2, Krzhizhanovskaya M.2
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隶属关系:
- Grebenshchikov Institute of Silicate Chemistry, Russian Academy of Sciences
- St. Petersburg State University
- 期: 卷 45, 编号 5 (2019)
- 页面: 395-397
- 栏目: Short Communications
- URL: https://journals.rcsi.science/1087-6596/article/view/217373
- DOI: https://doi.org/10.1134/S1087659619050043
- ID: 217373
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The thermal behavior of Na3H(SO4)2 is studied in the temperature range –180...220°C in a pre-vacuum. At 180°C, the compound decomposed into a mixture of phases: Na2SO4 (Cmcm), Na2SO4 (P63/mmc), Na2SO4 (Fddd), and Na2S2O7. The maximal thermal expansion was observed near the α33 axis. The anisotropy of thermal expansion sharply decreased together with the increase in temperature.
作者简介
N. Dmitrieva
Grebenshchikov Institute of Silicate Chemistry, Russian Academy of Sciences
Email: rimma_bubnova@mail.ru
俄罗斯联邦, St. Petersburg, 199034
R. Bubnova
Grebenshchikov Institute of Silicate Chemistry, Russian Academy of Sciences; St. Petersburg State University
编辑信件的主要联系方式.
Email: rimma_bubnova@mail.ru
俄罗斯联邦, St. Petersburg, 199034; St. Petersburg, 199034
S. Filatov
Grebenshchikov Institute of Silicate Chemistry, Russian Academy of Sciences
Email: rimma_bubnova@mail.ru
俄罗斯联邦, St. Petersburg, 199034
A. Shablinskii
Grebenshchikov Institute of Silicate Chemistry, Russian Academy of Sciences; St. Petersburg State University
Email: rimma_bubnova@mail.ru
俄罗斯联邦, St. Petersburg, 199034; St. Petersburg, 199034
M. Krzhizhanovskaya
St. Petersburg State University
Email: rimma_bubnova@mail.ru
俄罗斯联邦, St. Petersburg, 199034