Thermal Expansion and Phase Transitions in Na3H(SO4)2 Sulfate in the Low-Temperature Range


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The thermal behavior of Na3H(SO4)2 is studied in the temperature range –180...220°C in a pre-vacuum. At 180°C, the compound decomposed into a mixture of phases: Na2SO4 (Cmcm), Na2SO4 (P63/mmc), Na2SO4 (Fddd), and Na2S2O7. The maximal thermal expansion was observed near the α33 axis. The anisotropy of thermal expansion sharply decreased together with the increase in temperature.

作者简介

N. Dmitrieva

Grebenshchikov Institute of Silicate Chemistry, Russian Academy of Sciences

Email: rimma_bubnova@mail.ru
俄罗斯联邦, St. Petersburg, 199034

R. Bubnova

Grebenshchikov Institute of Silicate Chemistry, Russian Academy of Sciences; St. Petersburg State University

编辑信件的主要联系方式.
Email: rimma_bubnova@mail.ru
俄罗斯联邦, St. Petersburg, 199034; St. Petersburg, 199034

S. Filatov

Grebenshchikov Institute of Silicate Chemistry, Russian Academy of Sciences

Email: rimma_bubnova@mail.ru
俄罗斯联邦, St. Petersburg, 199034

A. Shablinskii

Grebenshchikov Institute of Silicate Chemistry, Russian Academy of Sciences; St. Petersburg State University

Email: rimma_bubnova@mail.ru
俄罗斯联邦, St. Petersburg, 199034; St. Petersburg, 199034

M. Krzhizhanovskaya

St. Petersburg State University

Email: rimma_bubnova@mail.ru
俄罗斯联邦, St. Petersburg, 199034


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