Effect of Formation Conditions on the Functional Composition of the Surface of High-Silica Porous Glass


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The possibility of controlling the content and ratio of Brønsted acid to Lewis base centers on the surface of high-silica porous glass (PG) with various compositions based on two-phase alkali-borosilicate glass by varying the conditions of the preparation of PG during the acid work-up of the initial glass is shown. The results demonstrate the possibility to control the features of the surface of the PG, and in particular, the ratio of silanol to siloxane structures.

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T. Tsyganova

Grebenshchikov Institute of Silicate Chemistry, Russian Academy of Sciences; St. Petersburg Scientific Center, Russian Academy of Sciences

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Email: Tsyganova2@yandex.ru
俄罗斯联邦, St. Petersburg, 199034; St. Petersburg, 199034

S. Myakin

St. Petersburg State Technological Institute (Technical University)

Email: Tsyganova2@yandex.ru
俄罗斯联邦, St. Petersburg, 190013

I. Kuryndin

Institute of High-Molecular Compounds, Russian Academy of Sciences

Email: Tsyganova2@yandex.ru
俄罗斯联邦, St. Petersburg, 199004

O. Rakhimova

St. Petersburg Electrotechnical University LETI

Email: Tsyganova2@yandex.ru
俄罗斯联邦, St. Petersburg, 197376

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