Study of Bismuth-Containing Composites Based on Thermally Modified Porous Glass with Low Additions of P2O5 and Fluorine Ions by the Near Infrared Spectroscopy Method
- Authors: Girsova M.A.1, Golovina G.F.1
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Affiliations:
- Grebenshchikov Institute of Silicate Chemistry, Russian Academy of Sciences
- Issue: Vol 44, No 6 (2018)
- Pages: 569-574
- Section: Article
- URL: https://journals.rcsi.science/1087-6596/article/view/216876
- DOI: https://doi.org/10.1134/S1087659618060068
- ID: 216876
Cite item
Abstract
Bismuth-containing composite materials are synthesized by the impregnation of matrices of thermally modified porous glass in 0.5 M water solutions of bismuth nitrate followed by the heat treatment of the bismuth-containing composite material in a wide temperature range of 50 to 870°C. The samples which differ by the regime of the thermal modification of porous glass (PG) (120, 400, and 600°C, duration 1 or 2 h) and the temperature of the heat treatment are studied by the near infrared spectroscopy. Dehydroxylation and glass surface concentration with impurity boron atoms occur with the growth of the heat treatment temperature. Bands caused by the absorption of Bi+ ions, bismuth active centers associated with silicon, and Bi4 and Bi3 bismuth dimers are found.
About the authors
M. A. Girsova
Grebenshchikov Institute of Silicate Chemistry, Russian Academy of Sciences
Author for correspondence.
Email: girsovamarina@rambler.ru
Russian Federation, St. Petersburg, 199034
G. F. Golovina
Grebenshchikov Institute of Silicate Chemistry, Russian Academy of Sciences
Email: girsovamarina@rambler.ru
Russian Federation, St. Petersburg, 199034