Shrinkage of Bismuth-Containing Porous Glass During the Sintering Process and the Viscosity of Quartz-Like Glass Based on Them


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Abstract

Shrinkage during the sintering of porous glass (PG) of different backgrounds and the viscosity of quartz-like glass (QG) sintered until the pores collapse are measured. The samples are obtained as a result of acid leaching of phase-separated sodium borosilicate glass. The initial PG and the samples that are doped with bismuth nitrate from a water-salt solution are studied. It is found that the heat treatment of the matrices at 750°C leads to an increase in their thermal stability. The viscosity of the matrices sintered at 870°C is practically independent of their pretreatment temperature. The viscosity of bismuth-containing quartz-like glass (BQG) decreases with an increase in the matrices’ treatment temperature.

About the authors

S. V. Stolyar

Grebenshchikov Institute of Silicate Chemistry, Russian Academy of Sciences

Author for correspondence.
Email: stolser@yandex.ru
Russian Federation, St. Petersburg, 199034

T. V. Antropova

Grebenshchikov Institute of Silicate Chemistry, Russian Academy of Sciences

Email: stolser@yandex.ru
Russian Federation, St. Petersburg, 199034

M. A. Girsova

Grebenshchikov Institute of Silicate Chemistry, Russian Academy of Sciences

Email: stolser@yandex.ru
Russian Federation, St. Petersburg, 199034

M. Yu. Konon

Grebenshchikov Institute of Silicate Chemistry, Russian Academy of Sciences

Email: stolser@yandex.ru
Russian Federation, St. Petersburg, 199034

I. N. Anfimova

Grebenshchikov Institute of Silicate Chemistry, Russian Academy of Sciences

Email: stolser@yandex.ru
Russian Federation, St. Petersburg, 199034

L. N. Kurilenko

Grebenshchikov Institute of Silicate Chemistry, Russian Academy of Sciences

Email: stolser@yandex.ru
Russian Federation, St. Petersburg, 199034


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