Photochromism of 3H-2,1,4-benzoxadiazine 4-oxides with heterocyclic substituents on the benzene ring


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详细

2H-Benzimidazole 1,3-dioxides undergo thermal isomerization to 3H-2,1,4-benzoxadiazine 4-oxides which are converted to 2H-benzimidazole 1-oxides on further heating. Irradiation of 3H-2,1,4-benzoxadiazine 4-oxides with sunlight induces their transformation to 2H-benzimidazole 1,3-dioxides. 3H-2,1,4-Benzoxadiazine 4-oxides containing nucleophilic heterocyclic substituents are considerably more stable to sunlight, and they can be used as photochromic compounds.

作者简介

E. Chugunova

Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center

编辑信件的主要联系方式.
Email: elena-chugunova@list.ru
俄罗斯联邦, ul. Arbuzova 8, Kazan Tatarstan, 420088

N. Akylbekov

Kazan National Research Technological University

Email: elena-chugunova@list.ru
俄罗斯联邦, ul. Karla Marksa 68, Kazan Tatarstan, 420015

V. Samsonov

Vorozhtsov Novosibirsk Institute of Organic Chemistry, Siberian Branch

Email: elena-chugunova@list.ru
俄罗斯联邦, pr. Akademika Lavrent’eva 9, Novosibirsk, 630090

S. Sitnov

Kazan Federal University

Email: elena-chugunova@list.ru
俄罗斯联邦, ul. Kremlevskaya 18, Kazan Tatarstan, 420008

A. Burilov

Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center

Email: elena-chugunova@list.ru
俄罗斯联邦, ul. Arbuzova 8, Kazan Tatarstan, 420088

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