Chemoselective Vinylation of the Quinine Hydroxy Group with the System Electron-Deficient Acetylene/Diphenylphosphine Oxide: an Alternative to SNHAr Reaction


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Three-component SNHAr reaction of quinine, diphenylphosphine oxide, and furoylacetylene chemoselectively afforded the corresponding quinine vinyl ether and 2: 1 adduct of diphenylphosphine oxide to the triple bond of furoylacetylene instead of the expected cross-coupling product at the pyridine ring.

作者简介

P. Volkov

Favorskii Irkutsk Institute of Chemistry, Siberian Branch

Email: boris_trofimov@irioch.irk.ru
俄罗斯联邦, Irkutsk, 664033

A. Telezhkin

Favorskii Irkutsk Institute of Chemistry, Siberian Branch

Email: boris_trofimov@irioch.irk.ru
俄罗斯联邦, Irkutsk, 664033

N. Ivanova

Favorskii Irkutsk Institute of Chemistry, Siberian Branch

Email: boris_trofimov@irioch.irk.ru
俄罗斯联邦, Irkutsk, 664033

K. Khrapova

Favorskii Irkutsk Institute of Chemistry, Siberian Branch

Email: boris_trofimov@irioch.irk.ru
俄罗斯联邦, Irkutsk, 664033

A. Albanov

Favorskii Irkutsk Institute of Chemistry, Siberian Branch

Email: boris_trofimov@irioch.irk.ru
俄罗斯联邦, Irkutsk, 664033

N. Gusarova

Favorskii Irkutsk Institute of Chemistry, Siberian Branch

Email: boris_trofimov@irioch.irk.ru
俄罗斯联邦, Irkutsk, 664033

B. Trofimov

Favorskii Irkutsk Institute of Chemistry, Siberian Branch

编辑信件的主要联系方式.
Email: boris_trofimov@irioch.irk.ru
俄罗斯联邦, Irkutsk, 664033

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