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Synthesis of 3-Aroyl-2-(polyfluoroalkyl)quinoxalines and 3-Aroyl-2-(polyfluoroalkyl)benzo[g]quinoxalines from Lithium 3-(Fluoroalkyl)-1,3-diketonates


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Abstract

A one-pot procedure has been developed for the synthesis of 3-aroyl-2-(polyfluoroalkyl)quinoxalines and 3-aroyl-2-(polyfluoroalkyl)benzo[g]quinoxalines by nitrosation of lithium 3-(polyfluoroalkyl)-1,3-diketonates and subsequent reaction with benzene-1,2-diamine or naphthalene-2,3-diamine, respectively.

About the authors

V. I. Filyakova

Postovskii Institute of Organic Synthesis, Ural Branch

Author for correspondence.
Email: filver@mail.ru
Russian Federation, Yekaterinburg

N. S. Boltacheva

Postovskii Institute of Organic Synthesis, Ural Branch

Email: filver@mail.ru
Russian Federation, Yekaterinburg

V. N. Charushin

Postovskii Institute of Organic Synthesis, Ural Branch

Email: filver@mail.ru
Russian Federation, Yekaterinburg

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