Synthesis of 3-Aroyl-2-(polyfluoroalkyl)quinoxalines and 3-Aroyl-2-(polyfluoroalkyl)benzo[ g ]quinoxalines from Lithium 3-(Fluoroalkyl)-1,3-diketonates

V. I. Filyakova; N. S. Boltacheva; V. N. Charushin

doi:10.1134/S107042801906023X

Synthesis of 3-Aroyl-2-(polyfluoroalkyl)quinoxalines and 3-Aroyl-2-(polyfluoroalkyl)benzo[g]quinoxalines from Lithium 3-(Fluoroalkyl)-1,3-diketonates

作者: Filyakova V.I.¹, Boltacheva N.S.¹, Charushin V.N.¹
隶属关系:
1. Postovskii Institute of Organic Synthesis, Ural Branch
期: 卷 55, 编号 6 (2019)
页面: 890-893
栏目: Short Communications
URL: https://journals.rcsi.science/1070-4280/article/view/220806
DOI: https://doi.org/10.1134/S107042801906023X
ID: 220806

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A one-pot procedure has been developed for the synthesis of 3-aroyl-2-(polyfluoroalkyl)quinoxalines and 3-aroyl-2-(polyfluoroalkyl)benzo[g]quinoxalines by nitrosation of lithium 3-(polyfluoroalkyl)-1,3-diketonates and subsequent reaction with benzene-1,2-diamine or naphthalene-2,3-diamine, respectively.