Email this article Gas-phase oxidation of propylene into acetone on a V2O5/TiO2 catalyst: Effect of pressure and role of water
- Authors: Chernov A.N.1, Sobolev V.I.1, Koltunov K.Y.1,2
-
Affiliations:
- Boreskov Institute of Catalysis, Siberian Branch
- Novosibirsk State University
- Issue: Vol 90, No 9 (2017)
- Pages: 1439-1442
- Section: Catalysis
- URL: https://journals.rcsi.science/1070-4272/article/view/215198
- DOI: https://doi.org/10.1134/S1070427217090105
- ID: 215198
Cite item
Open Access
Access granted
Subscription Access
Abstract
Positive effect of raising the pressure and water content in the reaction mixture in the oxidative conversion of propylene into acetone on a V2O5/TiO2 catalyst was observed. It was shown that the reaction occurs via intermediate formation of isopropanol, which id produced in situ as a result of the acid-catalyzed hydration of propylene and, under certain conditions, may be the main product.
About the authors
A. N. Chernov
Boreskov Institute of Catalysis, Siberian Branch
Email: koltunov@catalysis.ru
Russian Federation, pr. Akademika Lavrent’eva 5, Novosibirsk, 630090
V. I. Sobolev
Boreskov Institute of Catalysis, Siberian Branch
Email: koltunov@catalysis.ru
Russian Federation, pr. Akademika Lavrent’eva 5, Novosibirsk, 630090
K. Yu. Koltunov
Boreskov Institute of Catalysis, Siberian Branch; Novosibirsk State University
Author for correspondence.
Email: koltunov@catalysis.ru
Russian Federation, pr. Akademika Lavrent’eva 5, Novosibirsk, 630090; Novosibirsk, 630090
Supplementary files
