Enviar artigo por via de e-mail Gas-phase oxidation of propylene into acetone on a V2O5/TiO2 catalyst: Effect of pressure and role of water
- Autores: Chernov A.N.1, Sobolev V.I.1, Koltunov K.Y.1,2
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Afiliações:
- Boreskov Institute of Catalysis, Siberian Branch
- Novosibirsk State University
- Edição: Volume 90, Nº 9 (2017)
- Páginas: 1439-1442
- Seção: Catalysis
- URL: https://journals.rcsi.science/1070-4272/article/view/215198
- DOI: https://doi.org/10.1134/S1070427217090105
- ID: 215198
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Resumo
Positive effect of raising the pressure and water content in the reaction mixture in the oxidative conversion of propylene into acetone on a V2O5/TiO2 catalyst was observed. It was shown that the reaction occurs via intermediate formation of isopropanol, which id produced in situ as a result of the acid-catalyzed hydration of propylene and, under certain conditions, may be the main product.
Sobre autores
A. Chernov
Boreskov Institute of Catalysis, Siberian Branch
Email: koltunov@catalysis.ru
Rússia, pr. Akademika Lavrent’eva 5, Novosibirsk, 630090
V. Sobolev
Boreskov Institute of Catalysis, Siberian Branch
Email: koltunov@catalysis.ru
Rússia, pr. Akademika Lavrent’eva 5, Novosibirsk, 630090
K. Koltunov
Boreskov Institute of Catalysis, Siberian Branch; Novosibirsk State University
Autor responsável pela correspondência
Email: koltunov@catalysis.ru
Rússia, pr. Akademika Lavrent’eva 5, Novosibirsk, 630090; Novosibirsk, 630090
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