Catalytic properties of RhSe 2 /Ga/H-ZSM-5 system in the reaction of glycerol dehydration in the gas phase

S. V. Volkov; L. B. Khar’kova; S. A. Baranets; O. G. Yanko; P. E. Strizhak; G. R. Kosmambetova; V. I. Gritsenko

doi:10.1134/S1070427216020117

Catalytic properties of RhSe₂/Ga/H-ZSM-5 system in the reaction of glycerol dehydration in the gas phase

Authors: Volkov S.V.¹, Khar’kova L.B.¹, Baranets S.A.¹, Yanko O.G.¹, Strizhak P.E.², Kosmambetova G.R.², Gritsenko V.I.²
Affiliations:
1. Vernadsky Institute of General and Inorganic Chemistry
2. Pisarzhevskii Institute of Physical Chemistry
Issue: Vol 89, No 2 (2016)
Pages: 233-237
Section: Catalysis
URL: https://journals.rcsi.science/1070-4272/article/view/213557
DOI: https://doi.org/10.1134/S1070427216020117
ID: 213557

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Abstract

Catalytic properties of the RhSe₂/Ga/H-ZSM-5 system formed upon thermal treatment of a mechanical mixture of rhodium selenochloride Rh₂Se₉Cl₆ and a gallium-containing zeolite Ga/H-ZSM-5 at 300–340°C in a flow of nitrogen were studied in the course of glycerol dehydration in the gas phase. It was shown that the promotion of Ga/H-ZSM-5 with rhodium selenide RhSe₂ makes higher the yield of the target product acrolein.