Catalytic properties of RhSe2/Ga/H-ZSM-5 system in the reaction of glycerol dehydration in the gas phase


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Catalytic properties of the RhSe2/Ga/H-ZSM-5 system formed upon thermal treatment of a mechanical mixture of rhodium selenochloride Rh2Se9Cl6 and a gallium-containing zeolite Ga/H-ZSM-5 at 300–340°C in a flow of nitrogen were studied in the course of glycerol dehydration in the gas phase. It was shown that the promotion of Ga/H-ZSM-5 with rhodium selenide RhSe2 makes higher the yield of the target product acrolein.

Sobre autores

S. Volkov

Vernadsky Institute of General and Inorganic Chemistry

Autor responsável pela correspondência
Email: svyatium@mail.ru
Ucrânia, pr. Akademika Palladina 32/34, Kyiv, 03142

L. Khar’kova

Vernadsky Institute of General and Inorganic Chemistry

Email: svyatium@mail.ru
Ucrânia, pr. Akademika Palladina 32/34, Kyiv, 03142

S. Baranets

Vernadsky Institute of General and Inorganic Chemistry

Email: svyatium@mail.ru
Ucrânia, pr. Akademika Palladina 32/34, Kyiv, 03142

O. Yanko

Vernadsky Institute of General and Inorganic Chemistry

Email: svyatium@mail.ru
Ucrânia, pr. Akademika Palladina 32/34, Kyiv, 03142

P. Strizhak

Pisarzhevskii Institute of Physical Chemistry

Email: svyatium@mail.ru
Ucrânia, pr. Nauki 31, Kyiv, 03028

G. Kosmambetova

Pisarzhevskii Institute of Physical Chemistry

Email: svyatium@mail.ru
Ucrânia, pr. Nauki 31, Kyiv, 03028

V. Gritsenko

Pisarzhevskii Institute of Physical Chemistry

Email: svyatium@mail.ru
Ucrânia, pr. Nauki 31, Kyiv, 03028

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