Catalytic properties of RhSe2/Ga/H-ZSM-5 system in the reaction of glycerol dehydration in the gas phase
- Авторы: Volkov S.V.1, Khar’kova L.B.1, Baranets S.A.1, Yanko O.G.1, Strizhak P.E.2, Kosmambetova G.R.2, Gritsenko V.I.2
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Учреждения:
- Vernadsky Institute of General and Inorganic Chemistry
- Pisarzhevskii Institute of Physical Chemistry
- Выпуск: Том 89, № 2 (2016)
- Страницы: 233-237
- Раздел: Catalysis
- URL: https://journals.rcsi.science/1070-4272/article/view/213557
- DOI: https://doi.org/10.1134/S1070427216020117
- ID: 213557
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Аннотация
Catalytic properties of the RhSe2/Ga/H-ZSM-5 system formed upon thermal treatment of a mechanical mixture of rhodium selenochloride Rh2Se9Cl6 and a gallium-containing zeolite Ga/H-ZSM-5 at 300–340°C in a flow of nitrogen were studied in the course of glycerol dehydration in the gas phase. It was shown that the promotion of Ga/H-ZSM-5 with rhodium selenide RhSe2 makes higher the yield of the target product acrolein.
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S. Volkov
Vernadsky Institute of General and Inorganic Chemistry
Автор, ответственный за переписку.
Email: svyatium@mail.ru
Украина, pr. Akademika Palladina 32/34, Kyiv, 03142
L. Khar’kova
Vernadsky Institute of General and Inorganic Chemistry
Email: svyatium@mail.ru
Украина, pr. Akademika Palladina 32/34, Kyiv, 03142
S. Baranets
Vernadsky Institute of General and Inorganic Chemistry
Email: svyatium@mail.ru
Украина, pr. Akademika Palladina 32/34, Kyiv, 03142
O. Yanko
Vernadsky Institute of General and Inorganic Chemistry
Email: svyatium@mail.ru
Украина, pr. Akademika Palladina 32/34, Kyiv, 03142
P. Strizhak
Pisarzhevskii Institute of Physical Chemistry
Email: svyatium@mail.ru
Украина, pr. Nauki 31, Kyiv, 03028
G. Kosmambetova
Pisarzhevskii Institute of Physical Chemistry
Email: svyatium@mail.ru
Украина, pr. Nauki 31, Kyiv, 03028
V. Gritsenko
Pisarzhevskii Institute of Physical Chemistry
Email: svyatium@mail.ru
Украина, pr. Nauki 31, Kyiv, 03028
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