LiCl-Accelerated Nickel Catalyzed Cross-Coupling of Aryl Tosylates with the Aryl Grignard Reagents
- 作者: He X.1, Zhang Z.1, Li C.1, Li Y.1
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隶属关系:
- Department of Chemistry and Environmental Engineering
- 期: 卷 89, 编号 12 (2019)
- 页面: 2591-2596
- 栏目: Article
- URL: https://journals.rcsi.science/1070-3632/article/view/223258
- DOI: https://doi.org/10.1134/S1070363219120405
- ID: 223258
如何引用文章
详细
A mild coupling reaction catalyzed by Ni(acac)2-L4 has been studied. The catalyst acts efficiently in the reaction of biaryl coupling between various electrophiles and common or functionalized aryl Grignard reagents with high functional group tolerance. The study demonstrates that LiCl acts as an essential component in efficient cross-coupling by accelerating reduction of Ni(II) to Ni(0). The new catalytic system for selective couplings of aryl tosylates with aryl chlorides has been developed.
作者简介
Xiao-Yun He
Department of Chemistry and Environmental Engineering
编辑信件的主要联系方式.
Email: 61027391@qq.com
中国, Shijiazhuang, 050026
Zhi-Xun Zhang
Department of Chemistry and Environmental Engineering
Email: hebeihuagongyy@163.com
中国, Shijiazhuang, 050026
Chun-Jing Li
Department of Chemistry and Environmental Engineering
Email: hebeihuagongyy@163.com
中国, Shijiazhuang, 050026
Yan Li
Department of Chemistry and Environmental Engineering
编辑信件的主要联系方式.
Email: hebeihuagongyy@163.com
中国, Shijiazhuang, 050026
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