Structure of the Li+ Ion Close Environment in Various Solvents


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The literature data on various methods for studying structural characteristics of the Li+ ion close environment in a number of oxygen-containing solvents were generalized. The coordination numbers of the Li+ cation, interparticle distances, and types of ionic association were discussed. The number of coordinated solvent molecules and the Li+–O distance in the first coordination shell are independent of the nature of the considered solvents.

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P. Smirnov

G.A. Krestov Institute of Solution Chemistry of the Russian Academy of Sciences

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